American Chemical Society (ACS)
Organic Letters
,  том 11 ,  издание 1 ,  страницы 253-255

Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem

Тип публикации: Journal Article
Дата публикации: 2008-12-04
American Chemical Society (ACS)
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Arylvinyl ketones, under Morita-Baylis-Hillman (MBH) reaction conditions, produce a mixture of dimerization products. We propose a solution to this problem: a sila-MBH reaction. This cascade reaction involves addition of phosphine catalyst to arylvinyl ketones, trapping of the forming beta-silylenolate with aldehyde, followed by a 1,3-Brook rearrangement to give the Si-MBH adducts in good to excellent yields.
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Trofimov A., Gevorgyan V. Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem // Organic Letters. 2008. Vol. 11. No. 1. pp. 253-255.
ГОСТ со всеми авторами (до 50) Скопировать
Trofimov A., Gevorgyan V. Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem // Organic Letters. 2008. Vol. 11. No. 1. pp. 253-255.
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TY - JOUR
DO - 10.1021/ol8026522
UR - https://doi.org/10.1021/ol8026522
TI - Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem
T2 - Organic Letters
AU - Trofimov, A.B.
AU - Gevorgyan, Vladimir
PY - 2008
DA - 2008/12/04
PB - American Chemical Society (ACS)
SP - 253-255
IS - 1
VL - 11
PMID - 19055398
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
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@article{2008_Trofimov,
author = {A.B. Trofimov and Vladimir Gevorgyan},
title = {Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem},
journal = {Organic Letters},
year = {2008},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ol8026522},
number = {1},
pages = {253--255},
doi = {10.1021/ol8026522}
}
MLA
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Trofimov, A.B., and Vladimir Gevorgyan. “Sila-Morita−Baylis−Hillman Reaction of Arylvinyl Ketones: Overcoming the Dimerization Problem.” Organic Letters, vol. 11, no. 1, Dec. 2008, pp. 253-255. https://doi.org/10.1021/ol8026522.
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