volume 11 issue 11 pages 2269-2272

Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation.

Publication typeJournal Article
Publication date2009-05-08
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
PubMed ID:  19432414
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
(Hetero)aryl-, alkenyl-, and selected alkyl-substituted acid chlorides can be efficiently coupled with N-Boc-protected propargylamine to produce ynones which are converted in a one-pot fashion to 2-substituted N-Boc-4-iodopyrroles. Upon addition of a further alkyne, another Sonogashira coupling can be carried out in a one-pot fashion. This sequentially Pd/Cu-catalyzed process represents a very mild and efficient entry to 2,4-disubstituted N-Boc-pyrroles.
Found 
Found 

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GOST |
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GOST Copy
Merkul E. et al. Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation. // Organic Letters. 2009. Vol. 11. No. 11. pp. 2269-2272.
GOST all authors (up to 50) Copy
Merkul E., Boersch C., Frank W., Müller T. Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation. // Organic Letters. 2009. Vol. 11. No. 11. pp. 2269-2272.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ol900581a
UR - https://doi.org/10.1021/ol900581a
TI - Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation.
T2 - Organic Letters
AU - Merkul, Eugen
AU - Boersch, Christina
AU - Frank, Walter
AU - Müller, TJ
PY - 2009
DA - 2009/05/08
PB - American Chemical Society (ACS)
SP - 2269-2272
IS - 11
VL - 11
PMID - 19432414
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Merkul,
author = {Eugen Merkul and Christina Boersch and Walter Frank and TJ Müller},
title = {Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation.},
journal = {Organic Letters},
year = {2009},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ol900581a},
number = {11},
pages = {2269--2272},
doi = {10.1021/ol900581a}
}
MLA
Cite this
MLA Copy
Merkul, Eugen, et al. “Three-component synthesis of N-Boc-4-iodopyrroles and sequential one-pot alkynylation..” Organic Letters, vol. 11, no. 11, May. 2009, pp. 2269-2272. https://doi.org/10.1021/ol900581a.