volume 11 issue 24 pages 5642-5645

Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes

Publication typeJournal Article
Publication date2009-11-12
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
PubMed ID:  19908855
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A palladium-catalyzed decarboxylative [4 + 3] cyclization of gamma-methylidene-delta-valerolactones with 1,1-dicyanocyclopropanes has been developed to produce cycloheptane derivatives in a convergent manner. This method can be applied to the synthesis of azepanes by reacting with aziridines, and their asymmetric variants have also been described. In addition, selective ring-expansion reactions can be achieved for certain gamma-methylidene-delta-valerolactones to give nondecarboxylated nine-membered lactones.
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GOST Copy
Shintani R. et al. Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes // Organic Letters. 2009. Vol. 11. No. 24. pp. 5642-5645.
GOST all authors (up to 50) Copy
Shintani R., Murakami M., Tsuji T., TANNO H., Hayashi T. Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes // Organic Letters. 2009. Vol. 11. No. 24. pp. 5642-5645.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ol902326s
UR - https://doi.org/10.1021/ol902326s
TI - Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes
T2 - Organic Letters
AU - Shintani, Ryo
AU - Murakami, Masataka
AU - Tsuji, Takaoki
AU - TANNO, Hideyuki
AU - Hayashi, Tamio
PY - 2009
DA - 2009/11/12
PB - American Chemical Society (ACS)
SP - 5642-5645
IS - 24
VL - 11
PMID - 19908855
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Shintani,
author = {Ryo Shintani and Masataka Murakami and Takaoki Tsuji and Hideyuki TANNO and Tamio Hayashi},
title = {Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes},
journal = {Organic Letters},
year = {2009},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol902326s},
number = {24},
pages = {5642--5645},
doi = {10.1021/ol902326s}
}
MLA
Cite this
MLA Copy
Shintani, Ryo, et al. “Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes.” Organic Letters, vol. 11, no. 24, Nov. 2009, pp. 5642-5645. https://doi.org/10.1021/ol902326s.