Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond
Publication type: Journal Article
Publication date: 2001-02-16
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Iodo(aryl)palladium complexes, [PdI{C6H3(CF3)2-3,5}(N−N)] (N−N = tmeda, bpy, 4,4‘-dimethyl-2,2‘-bipyridine (Me2bpy)), react with AgBF4 in CH3CN, acetone, and THF to yield stable cationic arylpalladium complexes [Pd{C6H3(CF3)2-3,5}(N−N)(solv)]BF4. A similar reaction of AgBF4 with [PdI(C6H3Me2-3,5)(bpy)] in CH3CN gives [Pd(C6H3Me2-3,5)(bpy)(CH3CN)]BF4. The complex does not change its NMR spectrum for 1 h at room temperature in CD3CN but undergoes decomposition upon dissolution in acetone to release 3,3‘,5,5‘-tetramethylbiphenyl. Addition of AgBF4 to acetone or THF solutions of [PdI(Ar)(bpy)] (Ar = Ph, C6H3Me2-3,5) and of [PdI(Ar)(Me2bpy)] (Ar = C6H4OMe-4, C6H3Me2-3,5) does not lead to isolation of the cationic arylpalladium complexes and causes intermolecular coupling of the aryl ligands to yield the corresponding biaryls. The reaction of AgBF4 with [PdI(C6H3Me2-3,5)(bpy)] in the presence of an excess amount of dimethyl acetylenedicarboxylate (DMAD) in CH3CN gives [Pd(CZCZ−CZCZ−C6H3Me2-3,5)(bpy)(CH3CN)]BF4 ...
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Yagyu T. et al. Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond // Organometallics. 2001. Vol. 20. No. 6. pp. 1087-1101.
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Yagyu T., Hamada M., Osakada K., Yamamoto T. Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond // Organometallics. 2001. Vol. 20. No. 6. pp. 1087-1101.
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TY - JOUR
DO - 10.1021/om0007466
UR - https://doi.org/10.1021/om0007466
TI - Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond
T2 - Organometallics
AU - Yagyu, Takeyoshi
AU - Hamada, Makiko
AU - Osakada, Kohtaro
AU - Yamamoto, Takakazu
PY - 2001
DA - 2001/02/16
PB - American Chemical Society (ACS)
SP - 1087-1101
IS - 6
VL - 20
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2001_Yagyu,
author = {Takeyoshi Yagyu and Makiko Hamada and Kohtaro Osakada and Takakazu Yamamoto},
title = {Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond},
journal = {Organometallics},
year = {2001},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om0007466},
number = {6},
pages = {1087--1101},
doi = {10.1021/om0007466}
}
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Yagyu, Takeyoshi, et al. “Cationic Arylpalladium Complexes with Chelating Diamine Ligands, [PdAr(N−N)(solv)]BF4 (N−N = N,N,N‘,N‘-tetramethylethylenediamine, 2,2‘-bipyridine, 4,4‘-dimethyl-2,2‘-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allene into the Pd−C Bond.” Organometallics, vol. 20, no. 6, Feb. 2001, pp. 1087-1101. https://doi.org/10.1021/om0007466.