Organometallics

, том 20 , издание 6 , страницы 1223-1229

Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe₃)₂(SiMe₂C₅H₄N-2)

Тип публикации: Journal Article

Дата публикации: 2001-02-20

American Chemical Society (ACS)

Organometallics

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WOS Q2

БС1

SJR: 0.55

CiteScore: 4.6

Impact factor: 2.4

ISSN: 02767333, 15206041

DOI: 10.1021/om0009076

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

Reactions between LiC(SiMe3)(2)(SiMe2C5H4N-2), 1, and the halides GeCl2.dioxane, SnCl2, and PbCl2 gave the isostructural compounds MCl{C(SiMe3)(2)(SiMe2C5H4N-2)} (M = Ge, 2; Sn, 3; or Pb, 4) which contain three-coordinate M. Treatment of the tin derivative 3 with MeI gave the oxidative addition product SnMeClI{C(SiMe3)(2)(SiMe2C5H4N-2)}, 51 and this reacted with AgOCOCF3 or AgOSO2C6H4Me-4 to give, respectively, the compounds SnMeX2{C(SiMe3)(2)(SiMe2C5H4N-2)} with X = OCOCF3, 6, or OSO2C6H4Me-4, 7. Despite the presence of the bulky C(SiMe3)(2)(SiMe3C5H4N-2) ligand, the Sn atom in the solid state structures of 6 and 7 is five-coordinate, and multinuclear NMR studies show that five-coordinate species are present also in THF solutions of 5, 6, and 7.

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Organometallics	Organometallics, 9, 28.13% Organometallics 9 публикаций, 28.13%
Journal of Organometallic Chemistry	Journal of Organometallic Chemistry, 4, 12.5% Journal of Organometallic Chemistry 4 публикации, 12.5%
Dalton Transactions	Dalton Transactions, 3, 9.38% Dalton Transactions 3 публикации, 9.38%
Polyhedron	Polyhedron, 2, 6.25% Polyhedron 2 публикации, 6.25%
Russian Chemical Bulletin	Russian Chemical Bulletin, 1, 3.13% Russian Chemical Bulletin 1 публикация, 3.13%
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Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.13% Russian Chemical Reviews 1 публикация, 3.13%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 3.13% Coordination Chemistry Reviews 1 публикация, 3.13%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 1, 3.13% European Journal of Inorganic Chemistry 1 публикация, 3.13%
Applied Organometallic Chemistry	Applied Organometallic Chemistry, 1, 3.13% Applied Organometallic Chemistry 1 публикация, 3.13%
Inorganic Chemistry	Inorganic Chemistry, 1, 3.13% Inorganic Chemistry 1 публикация, 3.13%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 3.13% Journal of the American Chemical Society 1 публикация, 3.13%
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Advances in Heterocyclic Chemistry	Advances in Heterocyclic Chemistry, 1, 3.13% Advances in Heterocyclic Chemistry 1 публикация, 3.13%
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Al-Juaid S. S. et al. Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2) // Organometallics. 2001. Vol. 20. No. 6. pp. 1223-1229.

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Al-Juaid S. S., Avent A. G., Eaborn C., Hill M. S., Hitchcock P. B., Patel D. J., Smith J. Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2) // Organometallics. 2001. Vol. 20. No. 6. pp. 1223-1229.

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TY - JOUR

DO - 10.1021/om0009076

UR - https://doi.org/10.1021/om0009076

TI - Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2)

T2 - Organometallics

AU - Al-Juaid, Salih S.

AU - Avent, Anthony G.

AU - Eaborn, Colin

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Patel, Deepa J

AU - Smith, J.David

PY - 2001

DA - 2001/02/20

PB - American Chemical Society (ACS)

SP - 1223-1229

IS - 6

VL - 20

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2001_Al-Juaid,

author = {Salih S. Al-Juaid and Anthony G. Avent and Colin Eaborn and Michael S. Hill and Peter B. Hitchcock and Deepa J Patel and J.David Smith},

title = {Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2)},

journal = {Organometallics},

year = {2001},

volume = {20},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://doi.org/10.1021/om0009076},

number = {6},

pages = {1223--1229},

doi = {10.1021/om0009076}

}

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MLA Скопировать

Al-Juaid, Salih S., et al. “Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2).” Organometallics, vol. 20, no. 6, Feb. 2001, pp. 1223-1229. https://doi.org/10.1021/om0009076.

Издатель

American Chemical Society (ACS)

Журнал

Organometallics

SCImago Q2

WOS Q2

БС1

SJR

0.55

CiteScore

4.6

Impact factor