(Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization
Publication type: Journal Article
Publication date: 2002-06-21
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
[(η1-Flu)Ti(μ-OiPr)(OiPr)2]2 (1) and (η1-Flu)(η5-Flu)Ti(OiPr)2 (2) were easily prepared from FluLi and ClTi(iPrO)3 and demonstrated a remarkable thermal stability in comparison with known (fluorenyl)titanium complexes. Both complexes were characterized by X-ray analysis and temperature-dependent NMR spectroscopy. In combination with methylaluminoxane, both compounds are highly efficient initiators for styrene polymerization, producing highly syndiotactic polymers.
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Total citations:
28
Citations from 2024:
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(3%)
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GOST
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Knjazhanski S. Ya. et al. (Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization // Organometallics. 2002. Vol. 21. No. 15. pp. 3094-3099.
GOST all authors (up to 50)
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Lyssenko K. A. (Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization // Organometallics. 2002. Vol. 21. No. 15. pp. 3094-3099.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om011080y
UR - https://pubs.acs.org/doi/10.1021/om011080y
TI - (Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization
T2 - Organometallics
AU - Lyssenko, Konstantin A.
PY - 2002
DA - 2002/06/21
PB - American Chemical Society (ACS)
SP - 3094-3099
IS - 15
VL - 21
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Knjazhanski,
author = {Konstantin A. Lyssenko},
title = {(Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization},
journal = {Organometallics},
year = {2002},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/om011080y},
number = {15},
pages = {3094--3099},
doi = {10.1021/om011080y}
}
Cite this
MLA
Copy
Knjazhanski, Sergei Ya., et al. “(Fluorenyl)titanium triisopropoxide and bis(fluorenyl)titanium diisopropoxide: A facile synthesis, molecular structure, and catalytic activity in styrene polymerization.” Organometallics, vol. 21, no. 15, Jun. 2002, pp. 3094-3099. https://pubs.acs.org/doi/10.1021/om011080y.