Organometallics, volume 22, issue 17, pages 3608-3610

Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols

Publication typeJournal Article
Publication date2003-07-19
Journal: Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor2.8
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Secondary alcohols (carbinols) react with primary alcohols in dioxane at 80 °C in the presence of a catalytic amount of RuCl2(PPh3)3 and KOH along with a sacrificial hydrogen acceptor to afford the corresponding coupled secondary alcohols. The reaction is applicable to a wide range of aryl methyl, alkyl methyl, and cyclic carbinols, and with alkyl methyl carbinols, the alkylation took place exclusively at the less-hindered methyl position over β-methylene and -methine.

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GOST |
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GOST Copy
Cho C. S. et al. Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols // Organometallics. 2003. Vol. 22. No. 17. pp. 3608-3610.
GOST all authors (up to 50) Copy
Cho C. S., Kim B. T., Kim H. S., Kim T. J., Shim S. Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols // Organometallics. 2003. Vol. 22. No. 17. pp. 3608-3610.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/om030307h
UR - https://doi.org/10.1021/om030307h
TI - Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols
T2 - Organometallics
AU - Cho, Chan Sik
AU - Kim, Bok Tae
AU - Kim, Hong Seok
AU - Kim, Tae Jeong
AU - Shim, Sang-Chul
PY - 2003
DA - 2003/07/19 00:00:00
PB - American Chemical Society (ACS)
SP - 3608-3610
IS - 17
VL - 22
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex Copy
@article{2003_Cho,
author = {Chan Sik Cho and Bok Tae Kim and Hong Seok Kim and Tae Jeong Kim and Sang-Chul Shim},
title = {Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols},
journal = {Organometallics},
year = {2003},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/om030307h},
number = {17},
pages = {3608--3610},
doi = {10.1021/om030307h}
}
MLA
Cite this
MLA Copy
Cho, Chan Sik, et al. “Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols.” Organometallics, vol. 22, no. 17, Jul. 2003, pp. 3608-3610. https://doi.org/10.1021/om030307h.
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