Organometallics, volume 22, issue 17, pages 3608-3610
Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols
Publication type: Journal Article
Publication date: 2003-07-19
Journal:
Organometallics
Q1
Q2
SJR: 0.654
CiteScore: 5.6
Impact factor: 2.5
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Secondary alcohols (carbinols) react with primary alcohols in dioxane at 80 °C in the presence of a catalytic amount of RuCl2(PPh3)3 and KOH along with a sacrificial hydrogen acceptor to afford the corresponding coupled secondary alcohols. The reaction is applicable to a wide range of aryl methyl, alkyl methyl, and cyclic carbinols, and with alkyl methyl carbinols, the alkylation took place exclusively at the less-hindered methyl position over β-methylene and -methine.
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GOST
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Cho C. S. et al. Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols // Organometallics. 2003. Vol. 22. No. 17. pp. 3608-3610.
GOST all authors (up to 50)
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Cho C. S., Kim B. T., Kim H. S., Kim T. J., Shim S. Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols // Organometallics. 2003. Vol. 22. No. 17. pp. 3608-3610.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om030307h
UR - https://doi.org/10.1021/om030307h
TI - Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols
T2 - Organometallics
AU - Cho, Chan Sik
AU - Kim, Bok Tae
AU - Kim, Hong Seok
AU - Kim, Tae Jeong
AU - Shim, Sang-Chul
PY - 2003
DA - 2003/07/19
PB - American Chemical Society (ACS)
SP - 3608-3610
IS - 17
VL - 22
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Cho,
author = {Chan Sik Cho and Bok Tae Kim and Hong Seok Kim and Tae Jeong Kim and Sang-Chul Shim},
title = {Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols},
journal = {Organometallics},
year = {2003},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/om030307h},
number = {17},
pages = {3608--3610},
doi = {10.1021/om030307h}
}
Cite this
MLA
Copy
Cho, Chan Sik, et al. “Ruthenium-Catalyzed One-Pot β-Alkylation of Secondary Alcohols with Primary Alcohols.” Organometallics, vol. 22, no. 17, Jul. 2003, pp. 3608-3610. https://doi.org/10.1021/om030307h.