Organometallics, volume 23, issue 23, pages 5399-5401
Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand
Publication type: Journal Article
Publication date: 2004-10-13
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
SJR: 0.654
CiteScore: 5.6
Impact factor: 2.5
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A new N-heterocyclic carbene containing olefin metathesis catalyst, (sIMes)(Cl)_2Ru(CH(CH_2)_2-C,N-2-C_5H_4N) (4a), was synthesized from (sIMes)(PCy_3)(Cl)_2RuCHPh (1) or (sIMes)(py)_2(Cl)_2RuCHPh (3). When heated at 40 °C in dichloromethane, 4a is slowly converted to its isomer 4b. The X-ray structures of 4a and 4b show that the NHC and pyridine ligands are trans in 4a and cis in 4b. 4a is more latent than 1 and 4b much more latent than 4a in ring-closing metathesis (RCM) and ring-opening metathesis polymerization (ROMP).
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Ung T. et al. Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand // Organometallics. 2004. Vol. 23. No. 23. pp. 5399-5401.
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Ung T., Hejl A., Grubbs R. K., Schrodi Y. Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand // Organometallics. 2004. Vol. 23. No. 23. pp. 5399-5401.
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TY - JOUR
DO - 10.1021/om0493210
UR - https://doi.org/10.1021/om0493210
TI - Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand
T2 - Organometallics
AU - Ung, Thay
AU - Hejl, Andrew
AU - Grubbs, Robert K.
AU - Schrodi, Yann
PY - 2004
DA - 2004/10/13
PB - American Chemical Society (ACS)
SP - 5399-5401
IS - 23
VL - 23
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex
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@article{2004_Ung,
author = {Thay Ung and Andrew Hejl and Robert K. Grubbs and Yann Schrodi},
title = {Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand},
journal = {Organometallics},
year = {2004},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/om0493210},
number = {23},
pages = {5399--5401},
doi = {10.1021/om0493210}
}
Cite this
MLA
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Ung, Thay, et al. “Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand.” Organometallics, vol. 23, no. 23, Oct. 2004, pp. 5399-5401. https://doi.org/10.1021/om0493210.