Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene)
1
Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148
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Publication type: Journal Article
Publication date: 2005-05-26
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of saturated and unsaturated imidazolium salts with nickelocene in refluxing THF results in the formation of NHC complexes of general formula CpNi(NHC)Cl (NHC = SIMes (2), IPr (3), SIPr (4)). This protonation of Cp2Ni was also tested using phosphonium salts, and the reaction of nickelocene with triethylphosphonium chloride leads to CpNi(PEt3)Cl (5). All compounds were characterized by NMR and X-ray crystallography. The catalytic activity of the NHC compounds was tested in aryl amination (Buchwald−Hartwig reaction) and in aryl halide dehalogenation reactions.
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172
Total citations:
172
Citations from 2025:
8
(4.65%)
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Kelly R. A. et al. Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene) // Organometallics. 2005. Vol. 24. No. 14. pp. 3442-3447.
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Kelly R. A., Scott N. M., Diez-Gonzalez S., Stevens E. D., Nolan S. P. Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene) // Organometallics. 2005. Vol. 24. No. 14. pp. 3442-3447.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om0501879
UR - https://doi.org/10.1021/om0501879
TI - Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene)
T2 - Organometallics
AU - Kelly, Roy A.
AU - Scott, Natalie M.
AU - Diez-Gonzalez, Silvia
AU - Stevens, Edwin D.
AU - Nolan, Steven P.
PY - 2005
DA - 2005/05/26
PB - American Chemical Society (ACS)
SP - 3442-3447
IS - 14
VL - 24
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2005_Kelly,
author = {Roy A. Kelly and Natalie M. Scott and Silvia Diez-Gonzalez and Edwin D. Stevens and Steven P. Nolan},
title = {Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene)},
journal = {Organometallics},
year = {2005},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om0501879},
number = {14},
pages = {3442--3447},
doi = {10.1021/om0501879}
}
Cite this
MLA
Copy
Kelly, Roy A., et al. “Simple Synthesis of CpNi(NHC)Cl Complexes (Cp = Cyclopentadienyl; NHC = N-Heterocyclic Carbene).” Organometallics, vol. 24, no. 14, May. 2005, pp. 3442-3447. https://doi.org/10.1021/om0501879.