Organometallics, volume 25, issue 26, pages 6149-6154
Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes
Publication type: Journal Article
Publication date: 2006-11-14
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis of a series of ruthenium-based metathesis catalysts featuring imine donors chelated through the alkylidene group is described. The relative placement of the imine carbon−nitrogen double bond (exocyclic vs endocyclic) has a major impact on the initiation behavior. When used in metathesis applications, catalysts with an endocyclic imine bond show latent behavior and a high degree of tunability. The incorporation of additional donor atoms is an additional strategy for controlling initiation behavior. These latent catalysts could be useful in high-temperature applications.
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Citations by publishers
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1 publication, 0.95%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.95%
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Hejl A., Day M. W., Grubbs R. K. Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes // Organometallics. 2006. Vol. 25. No. 26. pp. 6149-6154.
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Hejl A., Day M. W., Grubbs R. K. Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes // Organometallics. 2006. Vol. 25. No. 26. pp. 6149-6154.
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TY - JOUR
DO - 10.1021/om060620u
UR - https://doi.org/10.1021/om060620u
TI - Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes
T2 - Organometallics
AU - Hejl, Andrew
AU - Day, Michael W.
AU - Grubbs, Robert K.
PY - 2006
DA - 2006/11/14 00:00:00
PB - American Chemical Society (ACS)
SP - 6149-6154
IS - 26
VL - 25
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2006_Hejl,
author = {Andrew Hejl and Michael W. Day and Robert K. Grubbs},
title = {Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes},
journal = {Organometallics},
year = {2006},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/om060620u},
number = {26},
pages = {6149--6154},
doi = {10.1021/om060620u}
}
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Hejl, Andrew, et al. “Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes.” Organometallics, vol. 25, no. 26, Nov. 2006, pp. 6149-6154. https://doi.org/10.1021/om060620u.