Ni(acac)2 /phosphine as an excellent precursor of nickel(0) for catalytic systems
Publication type: Journal Article
Publication date: 2010-06-30
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The coordination of phosphine ligands to nickel acetylacetonate was studied in toluene solution, and the first X-ray structure of the unstable complex trans-[Ni(acac)2(PMe2Ph)2] has been reported. A convenient procedure was developed to generate Ni(0) species in situ in solution from a Ni(acac)2 precursor, and their application in catalysis was demonstrated. A study of the reaction mechanism has suggested that water may play an important role in the formation of zerovalent nickel species. The nature of the Ni(0) species was confirmed by trapping with Ph2S2, and the structure of the resulting complexes trans-[Ni(SPh)2L2] was established by X-ray analysis for L = PMe2Ph, PMePh2, PBu3.
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Total citations:
52
Citations from 2024:
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(5%)
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MLA
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GOST
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Ananikov V. P. et al. Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems // Organometallics. 2010. Vol. 29. No. 21. pp. 5098-5102.
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Ananikov V. P., Gayduk K. A., Starikova Z. A., Beletskaya I. P. Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems // Organometallics. 2010. Vol. 29. No. 21. pp. 5098-5102.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om1003732
UR - https://doi.org/10.1021/om1003732
TI - Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems
T2 - Organometallics
AU - Ananikov, Valentine P.
AU - Gayduk, Konstantin A
AU - Starikova, Zoya A.
AU - Beletskaya, Irina P.
PY - 2010
DA - 2010/06/30
PB - American Chemical Society (ACS)
SP - 5098-5102
IS - 21
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Ananikov,
author = {Valentine P. Ananikov and Konstantin A Gayduk and Zoya A. Starikova and Irina P. Beletskaya},
title = {Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems},
journal = {Organometallics},
year = {2010},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/om1003732},
number = {21},
pages = {5098--5102},
doi = {10.1021/om1003732}
}
Cite this
MLA
Copy
Ananikov, Valentine P., et al. “Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems.” Organometallics, vol. 29, no. 21, Jun. 2010, pp. 5098-5102. https://doi.org/10.1021/om1003732.
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