Organometallics

, том 29 , издание 21 , страницы 5098-5102

Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems

Тип публикации: Journal Article

Дата публикации: 2010-06-30

American Chemical Society (ACS)

Organometallics

scimago Q2

wos Q1

БС1

SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/om1003732

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The coordination of phosphine ligands to nickel acetylacetonate was studied in toluene solution, and the first X-ray structure of the unstable complex trans-[Ni(acac)2(PMe2Ph)2] has been reported. A convenient procedure was developed to generate Ni(0) species in situ in solution from a Ni(acac)2 precursor, and their application in catalysis was demonstrated. A study of the reaction mechanism has suggested that water may play an important role in the formation of zerovalent nickel species. The nature of the Ni(0) species was confirmed by trapping with Ph2S2, and the structure of the resulting complexes trans-[Ni(SPh)2L2] was established by X-ray analysis for L = PMe2Ph, PMePh2, PBu3.

Найдено

1 цитирование

Карлинский Богдан

к.х.н.

18 публикаций, 245 цитирований, 82 рецензии

Индекс Хирша: 9

Институт органической химии им. Н.Д. Зелинского РАН

Тульский государственный университет

Области научных интересов

Зеленая химия

Катализ

Органическая химия

1 цитирование

Загидуллин Алмаз

🥼 🤝

к.х.н.

83 публикации, 936 цитирований

Индекс Хирша: 17

Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

Области научных интересов

Асимметрический металлокомплексный катализ

Координационная химия фосфора

Синтез хиральных фосфоросодержащих лигандов

Фосфорорганическая химия

Химия органических и элементоорганических соединений; химия полимеров; получение материалов

Элементоорганическая химия

1 цитирование

Сахапов Ильяс

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к.х.н.

44 публикации, 366 цитирований

Индекс Хирша: 12

Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

Области научных интересов

Зеленая химия

Электрохимия

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Ananikov V. P. et al. Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems // Organometallics. 2010. Vol. 29. No. 21. pp. 5098-5102.

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Ananikov V. P., Gayduk K. A., Starikova Z. A., Beletskaya I. P. Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems // Organometallics. 2010. Vol. 29. No. 21. pp. 5098-5102.

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TY - JOUR

DO - 10.1021/om1003732

UR - https://doi.org/10.1021/om1003732

TI - Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems

T2 - Organometallics

AU - Ananikov, Valentine P

AU - Gayduk, Konstantin A

AU - Starikova, Zoya A.

AU - Beletskaya, Irina P.

PY - 2010

DA - 2010/06/30

PB - American Chemical Society (ACS)

SP - 5098-5102

IS - 21

VL - 29

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2010_Ananikov,

author = {Valentine P Ananikov and Konstantin A Gayduk and Zoya A. Starikova and Irina P. Beletskaya},

title = {Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems},

journal = {Organometallics},

year = {2010},

volume = {29},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://doi.org/10.1021/om1003732},

number = {21},

pages = {5098--5102},

doi = {10.1021/om1003732}

}

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Ananikov, Valentine P., et al. “Ni(acac)2/phosphine as an excellent precursor of nickel(0) for catalytic systems.” Organometallics, vol. 29, no. 21, Jun. 2010, pp. 5098-5102. https://doi.org/10.1021/om1003732.