Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex
Publication type: Journal Article
Publication date: 2010-08-24
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Oxidation of (Idipp)AuMe (Idipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with I2 gives a monomethyl Au(III) complex, (Idipp)AuI2Me, which decomposes cleanly to MeI and (Idipp)AuI. Kinetics experiments show that this transformation occurs primarily via three-coordinate, cationic [(Idipp)AuIMe]+, which undergoes intramolecular reductive elimination rather than nucleophilic attack by external I−.
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Citations from 2024:
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GOST
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Scott V. J., Labinger J., Bercaw J. E. Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex // Organometallics. 2010. Vol. 29. No. 18. pp. 4090-4096.
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Scott V. J., Labinger J., Bercaw J. E. Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex // Organometallics. 2010. Vol. 29. No. 18. pp. 4090-4096.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om1006566
UR - https://doi.org/10.1021/om1006566
TI - Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex
T2 - Organometallics
AU - Scott, Valerie J
AU - Labinger, Jay
AU - Bercaw, John E.
PY - 2010
DA - 2010/08/24
PB - American Chemical Society (ACS)
SP - 4090-4096
IS - 18
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2010_Scott,
author = {Valerie J Scott and Jay Labinger and John E. Bercaw},
title = {Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex},
journal = {Organometallics},
year = {2010},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/om1006566},
number = {18},
pages = {4090--4096},
doi = {10.1021/om1006566}
}
Cite this
MLA
Copy
Scott, Valerie J., et al. “Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.” Organometallics, vol. 29, no. 18, Aug. 2010, pp. 4090-4096. https://doi.org/10.1021/om1006566.