Organometallics, volume 30, issue 5, pages 1130-1138

Ruthenium Olefin Metathesis Catalysts Containing Six-Membered Sulfone and Sulfonamide Chelating Rings

Anna Szadkowska ¹

Karolina Żukowska ^{1, 2}

Aleksandra E Pazio ²

Krzysztof Woźniak ²

Renat Kadyrov ³

Karol Grela ^{1, 2}

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Institute of Organic Chemistry, Polish Academy of Science, Kasprzaka 44/52, 01-224 Warsaw, Poland |

Department of Chemistry, University of Warsaw, Żwirki i Wigury Street 101, 02-089 Warsaw, Poland |

Evonik Degussa GmbH, 097-12a Rodenbacher Chaussee 4, 63457 Hanau-Wolfgang, Germany |

Publication type: Journal Article

Publication date: 2011-02-18

American Chemical Society (ACS)

Journal: Organometallics

scimago Q1

SJR: 0.654

CiteScore: 5.6

Impact factor: 2.5

ISSN: 02767333, 15206041

DOI: 10.1021/om101129b

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The preparation and X-ray structure characterization of new olefin metathesis initiators containing sulfone- and sulfonamide-substituted benzylidene ligands are described. We observed that these catalysts exhibit Ru···O(SO)R interactions, forming six-membered chelates. Tuning the electronic and steric factors of the benzylidene part as well as selecting the proper NHC ligands can have a direct impact on catalyst activity and stability, leading to promising new catalysts.

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Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q1

SJR

0.654

CiteScore

5.6

Impact factor

2.5

ISSN

02767333 (Print)

15206041 (Electronic)

Ruthenium Olefin Metathesis Catalysts Containing Six-Membered Sulfone and Sulfonamide Chelating Rings

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