Organometallics, volume 30, issue 12, pages 3430-3437
Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts
Publication type: Journal Article
Publication date: 2011-06-27
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis of novel sulfur-chelated ruthenium benzylidenes afforded latent catalysts with a wider range of activities and new isomeric forms. A ruthenium complex with a tridentate ligand displayed latency for even one of the most reactive ROMP monomers, dicyclopentadiene, while a room temperature latent trifluoromethyl-substituted thioether derivative was shown to be the most active sulfur-chelated precatalyst to date in several metathesis reactions at higher temperatures. These new complexes widen the spectrum of activity for this family of catalysts, enabling several practical applications and enhancing the understanding for the mechanisms of activation in strongly chelated ruthenium alkylidenes.
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Citations by publishers
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1 publication, 1.39%
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25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ginzburg Y. et al. Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts // Organometallics. 2011. Vol. 30. No. 12. pp. 3430-3437.
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Ginzburg Y., Anaby A., Vidavsky Y., Diesendruck C. E., Ben-Asuly A., Goldberg I., Lemcoff N. G. Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts // Organometallics. 2011. Vol. 30. No. 12. pp. 3430-3437.
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TY - JOUR
DO - 10.1021/om200323c
UR - https://doi.org/10.1021/om200323c
TI - Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts
T2 - Organometallics
AU - Ginzburg, Yakov
AU - Anaby, Aviel
AU - Ben-Asuly, Amos
AU - Vidavsky, Yuval
AU - Diesendruck, Charles E.
AU - Goldberg, Israel
AU - Lemcoff, N Gabriel
PY - 2011
DA - 2011/06/27 00:00:00
PB - American Chemical Society (ACS)
SP - 3430-3437
IS - 12
VL - 30
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2011_Ginzburg,
author = {Yakov Ginzburg and Aviel Anaby and Amos Ben-Asuly and Yuval Vidavsky and Charles E. Diesendruck and Israel Goldberg and N Gabriel Lemcoff},
title = {Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts},
journal = {Organometallics},
year = {2011},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/om200323c},
number = {12},
pages = {3430--3437},
doi = {10.1021/om200323c}
}
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MLA
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Ginzburg, Yakov, et al. “Widening the Latency Gap in Chelated Ruthenium Olefin Metathesis Catalysts.” Organometallics, vol. 30, no. 12, Jun. 2011, pp. 3430-3437. https://doi.org/10.1021/om200323c.