American Chemical Society (ACS)
Organometallics
,  том 31 ,  издание 3 ,  страницы 779-782

Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere

Тип публикации: Journal Article
Дата публикации: 2012-01-31
American Chemical Society (ACS)
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Two 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands with alkyl-substituted phosphines have been synthesized via a versatile method that allows for improved control of the phosphine substituent. The methyl- and benzyl-substituted phosphine P2N2 ligands (PMe2NPh2 and PBn2NPh2) were synthesized and characterized by 31P{1H} NMR, 1H NMR, and elemental analysis, and their corresponding [Ni(PR2NPh2)2](BF4)2 complexes were synthesized and characterized by 31P{1H} NMR, 1H NMR, and electrochemistry. The structure of the complex [Ni(PMe2NPh2)2](CF3SO3)2 was characterized by X-ray crystallography.
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Doud M. D. et al. Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere // Organometallics. 2012. Vol. 31. No. 3. pp. 779-782.
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Doud M. D., Grice K. A., Lilio A. M., Seu C. S., Kubiak C. P. Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere // Organometallics. 2012. Vol. 31. No. 3. pp. 779-782.
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TY - JOUR
DO - 10.1021/om201168h
UR - https://doi.org/10.1021/om201168h
TI - Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere
T2 - Organometallics
AU - Doud, Michael D
AU - Grice, Kyle A
AU - Lilio, Alyssia M
AU - Seu, Candace S.
AU - Kubiak, Clifford P.
PY - 2012
DA - 2012/01/31
PB - American Chemical Society (ACS)
SP - 779-782
IS - 3
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
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@article{2012_Doud,
author = {Michael D Doud and Kyle A Grice and Alyssia M Lilio and Candace S. Seu and Clifford P. Kubiak},
title = {Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/om201168h},
number = {3},
pages = {779--782},
doi = {10.1021/om201168h}
}
MLA
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Doud, Michael D., et al. “Versatile Synthesis of PR2NR′2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere.” Organometallics, vol. 31, no. 3, Jan. 2012, pp. 779-782. https://doi.org/10.1021/om201168h.