Organometallics

, том 31 , издание 17 , страницы 6312-6316

Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)₂in the Amination of Aryl Tosylates

Тип публикации: Journal Article

Дата публикации: 2012-08-08

American Chemical Society (ACS)

Organometallics

SCImago Q2

WOS Q1

БС1

SJR: 0.55

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/om300566m

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

A novel bis-styrene IPrNi0 derivative has been synthesized from the reaction of Ni(COD)2 and free 1,3-bis(2,6-diisopropylphenyl)imidazolidene (IPr) ligand in the presence of styrene. The complex has been characterized by spectroscopic data as well as by X-ray crystallography. Its catalytic performance in the amination reaction of aryl tosylates is also reported. The catalytic reactions proceed in a very selective manner, affording moderate to high yields of cross-coupling products in short reaction times at 110 °C.

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Iglesias M. J. et al. Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2in the Amination of Aryl Tosylates // Organometallics. 2012. Vol. 31. No. 17. pp. 6312-6316.

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Iglesias M. J., Blandez J. F., Fructos M. R., Prieto M. A., Álvarez E., Belderrain T. R., Nicasio M. C. Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2in the Amination of Aryl Tosylates // Organometallics. 2012. Vol. 31. No. 17. pp. 6312-6316.

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TY - JOUR

DO - 10.1021/om300566m

UR - https://doi.org/10.1021/om300566m

TI - Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2in the Amination of Aryl Tosylates

T2 - Organometallics

AU - Iglesias, María José

AU - Blandez, Juan F

AU - Fructos, Manuel R

AU - Prieto, María A.

AU - Álvarez, Eleuterio

AU - Belderrain, Tomás R.

AU - Nicasio, M C

PY - 2012

DA - 2012/08/08

PB - American Chemical Society (ACS)

SP - 6312-6316

IS - 17

VL - 31

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2012_Iglesias,

author = {María José Iglesias and Juan F Blandez and Manuel R Fructos and María A. Prieto and Eleuterio Álvarez and Tomás R. Belderrain and M C Nicasio},

title = {Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2in the Amination of Aryl Tosylates},

journal = {Organometallics},

year = {2012},

volume = {31},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/om300566m},

number = {17},

pages = {6312--6316},

doi = {10.1021/om300566m}

}

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MLA Скопировать

Iglesias, María José, et al. “Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2in the Amination of Aryl Tosylates.” Organometallics, vol. 31, no. 17, Aug. 2012, pp. 6312-6316. https://doi.org/10.1021/om300566m.

Издатель

American Chemical Society (ACS)

Журнал

Organometallics

SCImago Q2

WOS Q1

БС1

SJR

0.55

CiteScore

5.1

Impact factor