[Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst
Publication type: Journal Article
Publication date: 2012-09-06
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The preparation of the novel, well-defined [Pd(IPr*)(3-Cl-pyridinyl)Cl2] complex is described. The steric parameters of the ligand as well as its reactivity in the Buchwald–Hartwig amination were directly compared to other [Pd(NHC)(3-Cl-pyridinyl)Cl2] and [Pd(IPr*)(LX)Cl)] precatalysts (LX = cinnamyl or acac). The title complex exhibits similar catalytic activity to [Pd(NHC)(3-Cl-pyridinyl)Cl2] congeners (NHC = IPr and SIPr) at room temperature. However, it also showed improved reactivity at low catalyst loading and high temperature (as low as 0.025 mol %). On the other hand, it proved to be as efficient as the previously reported [Pd(IPr*)(cinnamyl)Cl] complex, pointing to the most likely existence of a similar catalytically active species.
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142
Total citations:
142
Citations from 2025:
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(4.23%)
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Chartoire A. et al. [Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst // Organometallics. 2012. Vol. 31. No. 19. pp. 6947-6951.
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Chartoire A., Frogneux X., Boreux A., Slawin A. M. Z., Nolan S. P. [Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst // Organometallics. 2012. Vol. 31. No. 19. pp. 6947-6951.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om300725f
UR - https://doi.org/10.1021/om300725f
TI - [Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst
T2 - Organometallics
AU - Chartoire, Anthony
AU - Frogneux, Xavier
AU - Boreux, Arnaud
AU - Slawin, Alexandra M. Z.
AU - Nolan, Steven P.
PY - 2012
DA - 2012/09/06
PB - American Chemical Society (ACS)
SP - 6947-6951
IS - 19
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Chartoire,
author = {Anthony Chartoire and Xavier Frogneux and Arnaud Boreux and Alexandra M. Z. Slawin and Steven P. Nolan},
title = {[Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/om300725f},
number = {19},
pages = {6947--6951},
doi = {10.1021/om300725f}
}
Cite this
MLA
Copy
Chartoire, Anthony, et al. “[Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst.” Organometallics, vol. 31, no. 19, Sep. 2012, pp. 6947-6951. https://doi.org/10.1021/om300725f.