Organometallics, volume 31, issue 19, pages 6972-6979
Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes
Publication type: Journal Article
Publication date: 2012-09-20
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The current article discusses the lability of the chloride ligands in cis-dichloro ruthenium benzylidene complexes featuring the NHC ligand N,N′-bis[2,4,6-(trimethyl)phenyl]imidazolin-2-ylidene] (SIMes) and an ester-chelating benzylidene ligand. A simple halide exchange reaction with iodide salts was used to assess the halide's lability in this type of complex. The starting compound bearing the cis-dichloro stereochemistry (cis-1) underwent rapid and selective exchange of the chloride trans to the SIMes ligand (cis-2). The substitution of the chloride cis to the NHC ligand for an iodide was found to be much slower, and the corresponding cis-diiodo compound could be isolated and characterized (cis-3). The latter compound undergoes fast and selective exchange of the iodide trans to the NHC ligand when an excess of a chloride source is added, and the fourth member of the family, bearing a chloride trans to the NHC ligand and a iodide cis to the NHC ligand (cis-4), was obtained. The four compounds have been f...
Top-30
Citations by journals
|
1
2
3
4
5
6
|
|
|
Organometallics
6 publications, 17.14%
|
|
|
Monatshefte fur Chemie
3 publications, 8.57%
|
|
|
Journal of Organometallic Chemistry
2 publications, 5.71%
|
|
|
Dalton Transactions
2 publications, 5.71%
|
|
|
Beilstein Journal of Organic Chemistry
1 publication, 2.86%
|
|
|
Catalysts
1 publication, 2.86%
|
|
|
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
1 publication, 2.86%
|
|
|
Polyhedron
1 publication, 2.86%
|
|
|
Chemistry of Heterocyclic Compounds
1 publication, 2.86%
|
|
|
Polymer
1 publication, 2.86%
|
|
|
Tetrahedron Letters
1 publication, 2.86%
|
|
|
Coordination Chemistry Reviews
1 publication, 2.86%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.86%
|
|
|
Angewandte Chemie
1 publication, 2.86%
|
|
|
Angewandte Chemie - International Edition
1 publication, 2.86%
|
|
|
Journal of the American Chemical Society
1 publication, 2.86%
|
|
|
Inorganic Chemistry
1 publication, 2.86%
|
|
|
Organic Chemistry Frontiers
1 publication, 2.86%
|
|
|
Catalysis Science and Technology
1 publication, 2.86%
|
|
|
Chemical Communications
1 publication, 2.86%
|
|
|
Chemistry - A European Journal
1 publication, 2.86%
|
|
|
Synthesis
1 publication, 2.86%
|
|
|
Russian Chemical Reviews
1 publication, 2.86%
|
|
|
1
2
3
4
5
6
|
Citations by publishers
|
1
2
3
4
5
6
7
8
|
|
|
American Chemical Society (ACS)
8 publications, 22.86%
|
|
|
Elsevier
6 publications, 17.14%
|
|
|
Wiley
6 publications, 17.14%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 14.29%
|
|
|
Springer Nature
4 publications, 11.43%
|
|
|
Beilstein-Institut
1 publication, 2.86%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 2.86%
|
|
|
Society of Synthetic Organic Chemistry
1 publication, 2.86%
|
|
|
Thieme
1 publication, 2.86%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.86%
|
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[4,8,4,3,1,2,1,4,5,0,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["11.43","22.86","11.43","8.57","2.86","5.71","2.86","11.43","14.29",0,"5.71","2.86"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organometallics","Monatshefte fur Chemie","Journal of Organometallic Chemistry","Dalton Transactions","Beilstein Journal of Organic Chemistry","Catalysts","Yuki Gosei Kagaku Kyokaishi\/Journal of Synthetic Organic Chemistry","Polyhedron","Chemistry of Heterocyclic Compounds","Polymer","Tetrahedron Letters","Coordination Chemistry Reviews","European Journal of Inorganic Chemistry","Angewandte Chemie","Angewandte Chemie - International Edition","Journal of the American Chemical Society","Inorganic Chemistry","Organic Chemistry Frontiers","Catalysis Science and Technology","Chemical Communications","Chemistry - A European Journal","Synthesis","Russian Chemical Reviews"],"ids":[1409,19838,11834,8473,21928,3739,3551,21269,16828,19955,6133,13437,15359,25450,19215,4813,24714,3991,2605,9073,24708,10934,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/ex6KJoZujZOZFZh7jGfeHauiftuB3CI7iwJVFRDg_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[6,3,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[17.14,8.57,5.71,5.71,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Elsevier","Wiley","Royal Society of Chemistry (RSC)","Springer Nature","Beilstein-Institut","Multidisciplinary Digital Publishing Institute (MDPI)","Society of Synthetic Organic Chemistry","Thieme","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,17,11,123,8,6139,202,1303,135,9422],"codes":[0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/ex6KJoZujZOZFZh7jGfeHauiftuB3CI7iwJVFRDg_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp","\/storage\/images\/resized\/xqixcltwJYe6H8Uco2JbAFfIOzt7UNKH0OcPOPzO_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[8,6,6,5,4,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[22.86,17.14,17.14,14.29,11.43,2.86,2.86,2.86,2.86,2.86],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,1,0,0,0],"percentage":["0","0","0","0","0","0","0","0","2.86","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,2,3,0,1,0,0,0,0,0,0,0],"percentage":["2.86","5.71","8.57","0","2.86","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,1,1,0,1,0,1,0,0,1,0],"percentage":["0","0","2.86","2.86","0","2.86","0","2.86","0","0","2.86","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3,4,0,2,0,1,1,3,3,0,1,1],"percentage":["8.57","11.43","0","5.71","0","2.86","2.86","8.57","8.57","0","2.86","2.86"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,0,0,0,0,0,0,1,0,0,0],"percentage":["0","5.71","0","0","0","0","0","0","2.86","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,1,0,0,0],"percentage":["0","0","0","0","0","0","0","0","2.86","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,1,3,0,0,0,0,0,0,0,0,0],"percentage":["2.86","2.86","8.57","0","0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,3,1,2,1,1,1,1,3,0,1,0],"percentage":["5.71","8.57","2.86","5.71","2.86","2.86","2.86","2.86","8.57","0","2.86","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,2,0,1,0,1,0,2,0,0,1,1],"percentage":["2.86","5.71","0","2.86","0","2.86","0","5.71","0","0","2.86","2.86"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,0,0,0,0,0,1,1,0,0,0],"percentage":["0","5.71","0","0","0","0","0","2.86","2.86","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Pump E., Fischer R., Slugovc C. Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes // Organometallics. 2012. Vol. 31. No. 19. pp. 6972-6979.
GOST all authors (up to 50)
Copy
Pump E., Fischer R., Slugovc C. Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes // Organometallics. 2012. Vol. 31. No. 19. pp. 6972-6979.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om300785t
UR - https://doi.org/10.1021/om300785t
TI - Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes
T2 - Organometallics
AU - Pump, Eva
AU - Fischer, R
AU - Slugovc, Christian
PY - 2012
DA - 2012/09/20 00:00:00
PB - American Chemical Society (ACS)
SP - 6972-6979
IS - 19
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex
Copy
@article{2012_Pump,
author = {Eva Pump and R Fischer and Christian Slugovc},
title = {Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/om300785t},
number = {19},
pages = {6972--6979},
doi = {10.1021/om300785t}
}
Cite this
MLA
Copy
Pump, Eva, et al. “Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes.” Organometallics, vol. 31, no. 19, Sep. 2012, pp. 6972-6979. https://doi.org/10.1021/om300785t.