Organometallics, volume 31, issue 19, pages 6972-6979
Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes
Publication type: Journal Article
Publication date: 2012-09-20
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The current article discusses the lability of the chloride ligands in cis-dichloro ruthenium benzylidene complexes featuring the NHC ligand N,N′-bis[2,4,6-(trimethyl)phenyl]imidazolin-2-ylidene] (SIMes) and an ester-chelating benzylidene ligand. A simple halide exchange reaction with iodide salts was used to assess the halide's lability in this type of complex. The starting compound bearing the cis-dichloro stereochemistry (cis-1) underwent rapid and selective exchange of the chloride trans to the SIMes ligand (cis-2). The substitution of the chloride cis to the NHC ligand for an iodide was found to be much slower, and the corresponding cis-diiodo compound could be isolated and characterized (cis-3). The latter compound undergoes fast and selective exchange of the iodide trans to the NHC ligand when an excess of a chloride source is added, and the fourth member of the family, bearing a chloride trans to the NHC ligand and a iodide cis to the NHC ligand (cis-4), was obtained. The four compounds have been f...
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Pump E., Fischer R., Slugovc C. Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes // Organometallics. 2012. Vol. 31. No. 19. pp. 6972-6979.
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Pump E., Fischer R., Slugovc C. Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes // Organometallics. 2012. Vol. 31. No. 19. pp. 6972-6979.
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TY - JOUR
DO - 10.1021/om300785t
UR - https://doi.org/10.1021/om300785t
TI - Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes
T2 - Organometallics
AU - Pump, Eva
AU - Fischer, R
AU - Slugovc, Christian
PY - 2012
DA - 2012/09/20 00:00:00
PB - American Chemical Society (ACS)
SP - 6972-6979
IS - 19
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex
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@article{2012_Pump,
author = {Eva Pump and R Fischer and Christian Slugovc},
title = {Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/om300785t},
number = {19},
pages = {6972--6979},
doi = {10.1021/om300785t}
}
Cite this
MLA
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Pump, Eva, et al. “Halide Exchange in Second-Generation cis-Dihalo Ruthenium Benzylidene Complexes.” Organometallics, vol. 31, no. 19, Sep. 2012, pp. 6972-6979. https://doi.org/10.1021/om300785t.