Organometallics

, volume 32 , issue 5 , pages 1272-1286

Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization

Dmitrii M. Roitershtein ^{1, 2}

Alexander A Vinogradov ^{2, 3}

Alexei A Vinogradov ^{1, 3}

Konstantin A. Lyssenko ⁴

Yulia V. Nelyubina ⁴

Ivan V Ananev ⁴

Ilya E. Nifant'ev ^{1, 5}

Vladimir A. Yakovlev ¹

Natalya N Kostitsyna ¹

Hide authors affiliations Show authors affiliations: 5 affiliations

A. V. Topchiev Institute of Petrochemical Synthesis, RAS, Leninsky pr. 29, Moscow, Russia 119991 |

L. Ya. Karpov Institute of Physical Chemistry, Obukha lane 3-1/12, Moscow, Russia 105064 |

N. D. Zelinsky Institute of Organic Chemistry, RAS, Leninsky pr. 47, Moscow, Russia 119991 |

⁴

A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, Vavilova str. 28, Moscow, Russia 119991 |

⁵

M. V. Lomonosov Chemistry Department, Moscow State University, Leninskie Gory 1-3, Moscow, Russia 119991 |

Publication type: Journal Article

Publication date: 2013-02-19

American Chemical Society (ACS)

Organometallics

scimago Q2

wos Q1

SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/om301020r

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

A new family of lanthanide complexes with di- and triphenylacetate ligands was prepared from LnCl3. Dimeric diphenylacetates were the only isolated products of the reaction between LnCl3 (Ln = La, Nd) and Ph2CHCOONa. The exchange reaction between LnCl3 and Ph3CCOONa led to the formation of three structurally different types of neodymium and lanthanum complexes under different reaction conditions. Various coordination modes of the carboxylate ligands were revealed, including κ2- and κ1-terminal coordination, μ2-κ1:κ1-bridging, and μ2-κ1:κ2-semibridging. The treatment of La and Nd tris-triphenylacetates with excess AlEt3 produces the dimeric tetraethylaluminates [Ln2((μ2-κ1:κ1-Ph3CCOO)4(AlEt4)2]. The structures of the key La and Nd triphenylacetates that were obtained from these reactions were verified by X-ray diffraction, and the complex [(THF)4Nd2(Ph2CHCOO)2(μ2-κ1:κ2-Ph2CHCOO)2(μ2- κ1:κ1-Ph2CHCOO)2] was studied by high-resolution X-ray diffraction. Neodymium di- and triphenylacetate complexes can serve a...

Found

7 citations

Lyssenko Konstantin

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Lomonosov Moscow State University

National Research University Higher School of Economics

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Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

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G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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h-index: 35

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National Research Centre "Kurchatov Institute"

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Vatsadze Sergey

DSc in Chemistry, professor, professor of the Russian Academy of Sciences

169 publications, 2 094 citations, 9 reviews

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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Fedorov Alexey

DSc in Chemistry, associate member of the Russian Academy of Sciences

93 publications, 2 810 citations, 10 reviews

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Saint Petersburg State University

1 citation

Nelyubina Yulia

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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Metal-organic frameworks

Quantum technologies

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Lyubov Dmitry

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G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Nyuchev Alexander

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Lobachevsky State University of Nizhny Novgorod

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Zubkov Fedor

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Peoples' Friendship University of Russia

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North Caucasus Federal University

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

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Samara State Technical University

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Mendeleev University of Chemical Technology of Russia

Gause Institute of New Antibiotics

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Roitershtein D. M. et al. Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization // Organometallics. 2013. Vol. 32. No. 5. pp. 1272-1286.

GOST all authors (up to 50) Copy

Roitershtein D. M., Vinogradov A. A., Vinogradov A. A., Lyssenko K. A., Nelyubina Y. V., Ananev I. V., Nifant'ev I. E., Yakovlev V. A., Kostitsyna N. N. Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization // Organometallics. 2013. Vol. 32. No. 5. pp. 1272-1286.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/om301020r

UR - https://pubs.acs.org/doi/10.1021/om301020r

TI - Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization

T2 - Organometallics

AU - Roitershtein, Dmitrii M.

AU - Vinogradov, Alexander A

AU - Vinogradov, Alexei A

AU - Lyssenko, Konstantin A.

AU - Nelyubina, Yulia V.

AU - Ananev, Ivan V

AU - Nifant'ev, Ilya E.

AU - Yakovlev, Vladimir A.

AU - Kostitsyna, Natalya N

PY - 2013

DA - 2013/02/19

PB - American Chemical Society (ACS)

SP - 1272-1286

IS - 5

VL - 32

SN - 0276-7333

SN - 1520-6041

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2013_Roitershtein,

author = {Dmitrii M. Roitershtein and Alexander A Vinogradov and Alexei A Vinogradov and Konstantin A. Lyssenko and Yulia V. Nelyubina and Ivan V Ananev and Ilya E. Nifant'ev and Vladimir A. Yakovlev and Natalya N Kostitsyna},

title = {Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization},

journal = {Organometallics},

year = {2013},

volume = {32},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://pubs.acs.org/doi/10.1021/om301020r},

number = {5},

pages = {1272--1286},

doi = {10.1021/om301020r}

}

MLA

Cite this

MLA Copy

Roitershtein, Dmitrii M., et al. “Di- and triphenylacetates of lanthanum and neodymium. Synthesis, structural diversity, and application in diene polymerization.” Organometallics, vol. 32, no. 5, Feb. 2013, pp. 1272-1286. https://pubs.acs.org/doi/10.1021/om301020r.

Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q2

wos Q1

SJR

0.676

CiteScore

5.1

Impact factor

2.9

ISSN

02767333 (Print)

15206041 (Electronic)

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