Organometallics, volume 31, issue 24, pages 8627-8638
Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies
Publication type: Journal Article
Publication date: 2012-12-11
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Hitherto unknown complexes of dimethyl cyclopropane-1,1-dicarboxylate with Lewis acids (Sn, Ti, and Ga chlorides) have been isolated and characterized. Their structures, which were previously assumed from theoretical considerations, have been confirmed, and the activating effect of Lewis acids on the cyclopropane ring has been shown experimentally. A single crystal of the complex with SnCl4 has been obtained, and an X-ray diffraction study has been performed. Hitherto unknown complexes of donor–acceptor cyclopropanes with GaCl3 belonging to a new type and having a 1,2-dipole (ylide) structure have been obtained and characterized. 1D and 2D NMR spectroscopy on 1H, 13C, 35Cl, 71Ga, and 119Sn nuclei were used to study the structures of the complexes. Furthermore, DOSY diffusion NMR spectroscopy was used to determine the diffusion coefficient in solution and the molecular masses of the complexes. The data obtained enrich the picture of transformations of donor–acceptor cyclopropanes widely used in organic syn...
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Citations by publishers
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1 publication, 1.59%
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5
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Novikov R. G. et al. Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies // Organometallics. 2012. Vol. 31. No. 24. pp. 8627-8638.
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Novikov R. G., Balakirev D. O., Timofeev V. P., Tomilov Y. V. Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies // Organometallics. 2012. Vol. 31. No. 24. pp. 8627-8638.
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TY - JOUR
DO - 10.1021/om301072v
UR - https://doi.org/10.1021/om301072v
TI - Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies
T2 - Organometallics
AU - Balakirev, Dmitry O.
AU - Timofeev, Vladimir P
AU - Novikov, Roman G.
AU - Tomilov, Yury V.
PY - 2012
DA - 2012/12/11 00:00:00
PB - American Chemical Society (ACS)
SP - 8627-8638
IS - 24
VL - 31
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2012_Novikov,
author = {Dmitry O. Balakirev and Vladimir P Timofeev and Roman G. Novikov and Yury V. Tomilov},
title = {Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies},
journal = {Organometallics},
year = {2012},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/om301072v},
number = {24},
pages = {8627--8638},
doi = {10.1021/om301072v}
}
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MLA
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Novikov, Roman G., et al. “Complexes of Donor–Acceptor Cyclopropanes with Tin, Titanium, and Gallium Chlorides — Mechanism Studies.” Organometallics, vol. 31, no. 24, Dec. 2012, pp. 8627-8638. https://doi.org/10.1021/om301072v.
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