Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands
Publication type: Journal Article
Publication date: 2013-05-10
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis of a series of Pd and Ni complexes containing combinations of 2-methylallyl (C4H7), cyclopentadienyl (C5H5, Cp), and indenyl (C7H9, Ind) ligands is reported. In all cases these complexes are supported by the electron-donating N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene (IPr). The mixed Cp/2-methylallyl complexes (η1-Cp)(η3-2-methylallyl)Pd(IPr) (CpAllPd) and (η5-Cp)(η1-2-methylallyl)Ni(IPr) (CpAllNi) were synthesized through the reaction of IPr with (Cp)(2-methylallyl)M (M = Ni, Pd). The binding mode of the ligands is different in the two complexes, and as a result the total valence electron count around the metal is 18 for the Ni complex and only 16 for the Pd species. In the case of Pd, an analogue of CpAllPd containing an indenyl ligand, (η1-Ind)(η3-2-methylallyl)Pd(IPr) (IndAllPd), was synthesized through the reaction of (η3-Ind)Pd(IPr)Cl (IndClPd) with (2-methylallyl)magnesium chloride. The corresponding Ni complex (η5-Ind)(η1-2-methyla...
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Bielinski E. A. et al. Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands // Organometallics. 2013. Vol. 32. No. 15. pp. 4025-4037.
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Bielinski E. A., Dai W., Guard L. M., Hazari N., Takase M. K. Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands // Organometallics. 2013. Vol. 32. No. 15. pp. 4025-4037.
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TY - JOUR
DO - 10.1021/om4002632
UR - https://doi.org/10.1021/om4002632
TI - Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands
T2 - Organometallics
AU - Bielinski, Elizabeth A
AU - Dai, Wei
AU - Guard, Louise M.
AU - Hazari, Nilay
AU - Takase, Michael K.
PY - 2013
DA - 2013/05/10
PB - American Chemical Society (ACS)
SP - 4025-4037
IS - 15
VL - 32
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Bielinski,
author = {Elizabeth A Bielinski and Wei Dai and Louise M. Guard and Nilay Hazari and Michael K. Takase},
title = {Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands},
journal = {Organometallics},
year = {2013},
volume = {32},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om4002632},
number = {15},
pages = {4025--4037},
doi = {10.1021/om4002632}
}
Cite this
MLA
Copy
Bielinski, Elizabeth A., et al. “Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands.” Organometallics, vol. 32, no. 15, May. 2013, pp. 4025-4037. https://doi.org/10.1021/om4002632.