Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges
Тип публикации: Journal Article
Дата публикации: 2013-07-15
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The magnetic metal-bridged fullerene dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2,η2-C60)2 was synthesized for the first time and studied by X-ray crystallography and magnetic susceptibility methods. The dimers, in which two fullerene C60 cages are η2-bonded through two Co0 atoms (S = 1/2), have a triplet (S = 1) state and transfer to a diamagnetic singlet (S = 0) ground state below 50 K (J/kB = −28.6 K). The theoretical calculations show that C60 can work as an efficient spin coupler between paramagnetic metals.
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Konarev D. V. et al. Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges // Organometallics. 2013. Vol. 32. No. 15. pp. 4038-4041.
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Konarev D. V., Troyanov S., Nakano Y., Ustimenko K. A., Otsuka A., Yamochi H., Saito G., Lyubovskaya R. N. Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges // Organometallics. 2013. Vol. 32. No. 15. pp. 4038-4041.
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TY - JOUR
DO - 10.1021/om400392c
UR - https://doi.org/10.1021/om400392c
TI - Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges
T2 - Organometallics
AU - Konarev, Dmitri V.
AU - Troyanov, Sergey
AU - Nakano, Yoshiaki
AU - Ustimenko, Ksenya A
AU - Otsuka, Akihiro
AU - Yamochi, H.
AU - Saito, Gunzi
AU - Lyubovskaya, Rimma N.
PY - 2013
DA - 2013/07/15
PB - American Chemical Society (ACS)
SP - 4038-4041
IS - 15
VL - 32
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2013_Konarev,
author = {Dmitri V. Konarev and Sergey Troyanov and Yoshiaki Nakano and Ksenya A Ustimenko and Akihiro Otsuka and H. Yamochi and Gunzi Saito and Rimma N. Lyubovskaya},
title = {Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges},
journal = {Organometallics},
year = {2013},
volume = {32},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/om400392c},
number = {15},
pages = {4038--4041},
doi = {10.1021/om400392c}
}
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Konarev, Dmitri V., et al. “Magnetic Coupling in the Fullerene Dimer {Co(Ph3P)(C6H5CN)}2(μ2-η2:η2-C60)2 with Two Zerovalent Cobalt Atoms as Bridges.” Organometallics, vol. 32, no. 15, Jul. 2013, pp. 4038-4041. https://doi.org/10.1021/om400392c.