Organometallics

, volume 27 , issue 6 , pages 1259-1266

Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines

Andrew R Shaffer ¹

Joseph A R Schmidt ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Chemistry, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, Ohio 43606-3390 |

Publication type: Journal Article

Publication date: 2008-02-27

American Chemical Society (ACS)

Organometallics

scimago Q2

wos Q1

SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/om701106q

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Palladium(II) 3-iminophosphine derivatives were screened as intermolecular hydroamination catalysts, with (3-iminophosphine)(allyl)palladium triflate determined to be the most active for the hydroamination of 1,3-cyclohexadiene and phenylacetylene. The iminophosphine ligands were synthesized by a three-step process and coordinated in an η2 and η1 manner to palladium(II) chloride and (allyl)palladium(II) chloride, respectively.

Found

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Skatova Alexandra

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G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Pallaeva Tatiana

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Kurchatov Complex of Crystallography and Photonics of NRC «Kurchatov Institute»

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Research interests

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Shaffer A. R., Schmidt J. A. R. Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines // Organometallics. 2008. Vol. 27. No. 6. pp. 1259-1266.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/om701106q

UR - https://doi.org/10.1021/om701106q

TI - Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines

T2 - Organometallics

AU - Shaffer, Andrew R

AU - Schmidt, Joseph A R

PY - 2008

DA - 2008/02/27

PB - American Chemical Society (ACS)

SP - 1259-1266

IS - 6

VL - 27

SN - 0276-7333

SN - 1520-6041

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2008_Shaffer,

author = {Andrew R Shaffer and Joseph A R Schmidt},

title = {Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines},

journal = {Organometallics},

year = {2008},

volume = {27},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://doi.org/10.1021/om701106q},

number = {6},

pages = {1259--1266},

doi = {10.1021/om701106q}

}

MLA

Cite this

MLA Copy

Shaffer, Andrew R., and Joseph A R Schmidt. “Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines.” Organometallics, vol. 27, no. 6, Feb. 2008, pp. 1259-1266. https://doi.org/10.1021/om701106q.

Publisher

American Chemical Society (ACS)

Journal

Organometallics

scimago Q2

wos Q1

SJR

0.676

CiteScore

5.1

Impact factor

2.9

ISSN

02767333 (Print)

15206041 (Electronic)