Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Pavel A. Dub
1
,
Gleb A Silantyev
1
,
Lina M. epstein
1
,
Elena S. Shubina
1
,
Jean-Claude Daran
1
,
Publication type: Journal Article
Publication date: 2008-05-30
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The previously undescribed complex Cp*Os(dppe)H was synthesized starting from either K2OsX6 salts or H2OsBr6 and characterized together with its precursors Cp*Os(COD)X (X = Cl, Br). Protonation of 1 by HBF4·Et2O was studied in CD2Cl2 at 193 K and was found to lead exclusively to cis-[Cp*Os(dppe)(H)2]+BF4−, which irreversibly transforms into trans-[Cp*Os(dppe)(H)2]+BF4− above 230 K.
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GOST
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Dub P. A. et al. Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control // Organometallics. 2008. Vol. 27. No. 13. pp. 3307-3311.
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Dub P. A., belkova N. V., Lyssenko K. A., Silantyev G. A., epstein L. M., Shubina E. S., Daran J., Poli R. Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control // Organometallics. 2008. Vol. 27. No. 13. pp. 3307-3311.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om8000235
UR - https://doi.org/10.1021/om8000235
TI - Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
T2 - Organometallics
AU - Dub, Pavel A.
AU - belkova, Natalia V.
AU - Lyssenko, Konstantin A.
AU - Silantyev, Gleb A
AU - epstein, Lina M.
AU - Shubina, Elena S.
AU - Daran, Jean-Claude
AU - Poli, Rinaldo
PY - 2008
DA - 2008/05/30
PB - American Chemical Society (ACS)
SP - 3307-3311
IS - 13
VL - 27
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2008_Dub,
author = {Pavel A. Dub and Natalia V. belkova and Konstantin A. Lyssenko and Gleb A Silantyev and Lina M. epstein and Elena S. Shubina and Jean-Claude Daran and Rinaldo Poli},
title = {Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control},
journal = {Organometallics},
year = {2008},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om8000235},
number = {13},
pages = {3307--3311},
doi = {10.1021/om8000235}
}
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MLA
Copy
Dub, Pavel A., et al. “Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control.” Organometallics, vol. 27, no. 13, May. 2008, pp. 3307-3311. https://doi.org/10.1021/om8000235.
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