Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
V. A. Kozlov
1
,
Yu V Nelyubina
1
,
E I Gutsul
1
,
L.N. Puntus
1
,
A. A. Vasilev
1
,
P.V Petrovskii
1
,
I. L. Odinets
1
Publication type: Journal Article
Publication date: 2008-07-25
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Treatment of the 3-diphenylphosphorylbenzoic acid amides 3a,b with the Lawesson reagent resulted in 3-diphenylthiophosphorylbenzoic acid thioamides 4a,b, which easily underwent cyclopalladation at the C-2 position of the central benzene ring to give new hybrid pincer complexes 5a,b with κ3-SCS coordination. Molecular structures of the complexes were characterized by X-ray diffraction. The peculiarities of chemical bonding in 5a were investigated via topological analysis of charge density in the crystal. The palladium complexes 5a,b demonstrated high catalytic activity for the Suzuki cross-coupling reactions of aryl bromides with phenylboronic acid and exhibited luminescence at 77 and 300 K.
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70
Total citations:
70
Citations from 2024:
2
(2.86%)
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Kozlov V. A. et al. Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties // Organometallics. 2008. Vol. 27. No. 16. pp. 4062-4070.
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Kozlov V. A., V. Aleksanyan D., Nelyubina Yu. V., Lyssenko K. A., Gutsul E. I., Puntus L., Vasilev A. A., Petrovskii P., Odinets I. L. Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties // Organometallics. 2008. Vol. 27. No. 16. pp. 4062-4070.
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TY - JOUR
DO - 10.1021/om8002762
UR - https://doi.org/10.1021/om8002762
TI - Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
T2 - Organometallics
AU - Kozlov, V. A.
AU - V. Aleksanyan, Diana
AU - Nelyubina, Yu V
AU - Lyssenko, Konstantin A.
AU - Gutsul, E I
AU - Puntus, L.N.
AU - Vasilev, A. A.
AU - Petrovskii, P.V
AU - Odinets, I. L.
PY - 2008
DA - 2008/07/25
PB - American Chemical Society (ACS)
SP - 4062-4070
IS - 16
VL - 27
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Kozlov,
author = {V. A. Kozlov and Diana V. Aleksanyan and Yu V Nelyubina and Konstantin A. Lyssenko and E I Gutsul and L.N. Puntus and A. A. Vasilev and P.V Petrovskii and I. L. Odinets},
title = {Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties},
journal = {Organometallics},
year = {2008},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/om8002762},
number = {16},
pages = {4062--4070},
doi = {10.1021/om8002762}
}
Cite this
MLA
Copy
Kozlov, V. A., et al. “Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties.” Organometallics, vol. 27, no. 16, Jul. 2008, pp. 4062-4070. https://doi.org/10.1021/om8002762.
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