Organometallics

, том 28 , издание 12 , страницы 3449-3458

Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity

Тип публикации: Journal Article

Дата публикации: 2009-05-04

American Chemical Society (ACS)

Organometallics

scimago Q2

wos Q1

БС1

SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/om9001389

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

Reactions of titanium and yttrium trichlorides with 1 equiv of the sodium or potassium salts of the diamine bis(phenolate) H2tBu2O2NN′ (Me2NCH2CH2-(CH2-2-HO-3,5-C6H2tBu2)2) led to formation of [TiCl(tBu2O2NN′)(L)] (L = THF, 1; py, 2) and [YCl(tBu2O2NN′)(DME)], 3. Reactions of 1 or 3 with MCH2-(2-NMe2)C6H4 and with M[2-(CH2NMe2)C6H4] (M = Li, K) led to [Ti(tBu2O2NN′)(κ2-(CH2C6H4NMe2))], 5, [Y(tBu2O2NN′)(κ2-(CH2C6H4NMe2))], 6, and [Y(tBu2O2NN′)(κ2-(C6H4CH2NMe2))], 7. [Y(tBu2O2NN′)N(SiMe3)2], 4, was obtained from 3 and KN(SiMe3)2, whereas [(Y(tBu2O2NN′)(CH2SiMe3))2(μ4-O)(μ3-Li)2], 8, formed from reaction of 3 and LiCH2SiMe3. The reaction of 7 with 1 equiv of CH3CN gave [Y(tBu2O2NN′)(NC(CH3)C6H4CH2NMe2)], 10, which displays a chelating ketimide ligand formed by nitrile insertion in the Y−Ph bond. Further reaction with CH3CN led to [Y(tBu2O2NN′)(κ2-(N(H)C(CH3)C(H)C(C6H4CH2NMe2)N(H)], 9, the formation of which involves an imine−enamine tautomerism followed by a second nitrile insertion and 1,3-hydrogen shift. T...

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Barroso S. et al. Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity // Organometallics. 2009. Vol. 28. No. 12. pp. 3449-3458.

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Barroso S., Cui J., Carretas J., Cruz A., Santos I., Duarte M. J., Telo J. P., Marques N., Martins A. M. Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity // Organometallics. 2009. Vol. 28. No. 12. pp. 3449-3458.

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TY - JOUR

DO - 10.1021/om9001389

UR - https://doi.org/10.1021/om9001389

TI - Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity

T2 - Organometallics

AU - Barroso, Sónia

AU - Cui, Jinlan

AU - Carretas, José

AU - Cruz, Adelaide

AU - Santos, Isabel A.

AU - Duarte, M. Jazmin

AU - Telo, João P.

AU - Marques, Noémia

AU - Martins, A. M.

PY - 2009

DA - 2009/05/04

PB - American Chemical Society (ACS)

SP - 3449-3458

IS - 12

VL - 28

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2009_Barroso,

author = {Sónia Barroso and Jinlan Cui and José Carretas and Adelaide Cruz and Isabel A. Santos and M. Jazmin Duarte and João P. Telo and Noémia Marques and A. M. Martins},

title = {Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity},

journal = {Organometallics},

year = {2009},

volume = {28},

publisher = {American Chemical Society (ACS)},

month = {may},

url = {https://doi.org/10.1021/om9001389},

number = {12},

pages = {3449--3458},

doi = {10.1021/om9001389}

}

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Barroso, Sónia, et al. “Diamine Bis(phenolate) M(III) (Y, Ti) Complexes: Synthesis, Structures, and Reactivity.” Organometallics, vol. 28, no. 12, May. 2009, pp. 3449-3458. https://doi.org/10.1021/om9001389.