Organometallics, volume 28, issue 16, pages 4652-4655

Photoactivation of Ruthenium Olefin Metathesis Initiators

Publication typeJournal Article
Publication date2009-07-24
Journal: Organometallics
scimago Q1
SJR0.654
CiteScore5.6
Impact factor2.5
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro−trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.
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