Organometallics

, том 28 , издание 20 , страницы 6003-6013

Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

Тип публикации: Journal Article

Дата публикации: 2009-09-23

American Chemical Society (ACS)

Organometallics

SCImago Q2

WOS Q1

БС1

SJR: 0.55

CiteScore: 4.6

Impact factor: 2.4

ISSN: 02767333, 15206041

DOI: 10.1021/om900490b

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe3, and AlMe3/[CPh3][B(C6F5)4] has been studied by 1H, 2H, and 19F NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.

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Soshnikov I. E. et al. Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts // Organometallics. 2009. Vol. 28. No. 20. pp. 6003-6013.

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Soshnikov I. E., Semikolenova N. V., Bushmelev A. N., Bryliakov K. P., Lyakin O. Y., Redshaw C., Zakharov V. A., Talsi E. P. Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts // Organometallics. 2009. Vol. 28. No. 20. pp. 6003-6013.

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TY - JOUR

DO - 10.1021/om900490b

UR - https://doi.org/10.1021/om900490b

TI - Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

T2 - Organometallics

AU - Soshnikov, Igor E

AU - Semikolenova, Nina V

AU - Bushmelev, Alexey N

AU - Bryliakov, Konstantin P.

AU - Lyakin, Oleg Y

AU - Redshaw, Carl

AU - Zakharov, Vladimir A

AU - Talsi, Evgenii P

PY - 2009

DA - 2009/09/23

PB - American Chemical Society (ACS)

SP - 6003-6013

IS - 20

VL - 28

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2009_Soshnikov,

author = {Igor E Soshnikov and Nina V Semikolenova and Alexey N Bushmelev and Konstantin P. Bryliakov and Oleg Y Lyakin and Carl Redshaw and Vladimir A Zakharov and Evgenii P Talsi},

title = {Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts},

journal = {Organometallics},

year = {2009},

volume = {28},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021/om900490b},

number = {20},

pages = {6003--6013},

doi = {10.1021/om900490b}

}

MLA

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MLA Скопировать

Soshnikov, Igor E., et al. “Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts.” Organometallics, vol. 28, no. 20, Sep. 2009, pp. 6003-6013. https://doi.org/10.1021/om900490b.

Издатель

American Chemical Society (ACS)

Журнал

Organometallics

SCImago Q2

WOS Q1

БС1

SJR

0.55

CiteScore

4.6

Impact factor