Organometallics, volume 29, issue 1, pages 250-256
Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes
Publication type: Journal Article
Publication date: 2009-11-06
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The first examples of ruthenium-based olefin metathesis catalysts containing acyclic diaminocarbene (ADC) ligands are reported. Complexes of the type (ADC)(SIMes)Cl2Ru═CHPh and (ADC)Cl2Ru═CH(2-isopropoxy)Ph (ADC = N,N′-dimesityl-N,N′-dimethylformamidin-2-ylidene or N,N′-bis(2,6-di-isopropylphenyl)-N,N′-dimethylformamidin-2-ylidene; SIMes = 1,3-dimesitylimidazolin-2-ylidene) were synthesized and studied in solution as well as in the solid state. Depending on their N-substituents and the metal center to which they were coordinated, the aforementioned ADC ligands were found to adopt different conformations. Preliminary investigations revealed that these Ru complexes exhibited high catalytic activities in a variety of olefin metathesis reactions at elevated temperatures and afforded cross-metathesis products with significantly lower E:Z ratios than catalysts containing analogous N-heterocyclic carbene ligands.
Top-30
Citations by journals
|
2
4
6
8
10
12
14
|
|
|
Organometallics
14 publications, 22.95%
|
|
|
Journal of the American Chemical Society
3 publications, 4.92%
|
|
|
Dalton Transactions
3 publications, 4.92%
|
|
|
Coordination Chemistry Reviews
2 publications, 3.28%
|
|
|
Inorganic Chemistry Frontiers
2 publications, 3.28%
|
|
|
Journal of Organometallic Chemistry
2 publications, 3.28%
|
|
|
Chemical Communications
2 publications, 3.28%
|
|
|
Inorganic Chemistry
1 publication, 1.64%
|
|
|
Russian Journal of Inorganic Chemistry
1 publication, 1.64%
|
|
|
Zeitschrift fur Kristallographie - Crystalline Materials
1 publication, 1.64%
|
|
|
Molecules
1 publication, 1.64%
|
|
|
Tetrahedron
1 publication, 1.64%
|
|
|
Journal of Catalysis
1 publication, 1.64%
|
|
|
Catalysis Communications
1 publication, 1.64%
|
|
|
Polyhedron
1 publication, 1.64%
|
|
|
Applied Catalysis A: General
1 publication, 1.64%
|
|
|
Advanced Synthesis and Catalysis
1 publication, 1.64%
|
|
|
Angewandte Chemie - International Edition
1 publication, 1.64%
|
|
|
Angewandte Chemie
1 publication, 1.64%
|
|
|
Applied Organometallic Chemistry
1 publication, 1.64%
|
|
|
ChemCatChem
1 publication, 1.64%
|
|
|
Organic Letters
1 publication, 1.64%
|
|
|
Journal of Physical Chemistry A
1 publication, 1.64%
|
|
|
ACS Catalysis
1 publication, 1.64%
|
|
|
Green Chemistry
1 publication, 1.64%
|
|
|
Annual Reports Section B (Organic Chemistry)
1 publication, 1.64%
|
|
|
Chemical Science
1 publication, 1.64%
|
|
|
New Journal of Chemistry
1 publication, 1.64%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 1.64%
|
|
|
2
4
6
8
10
12
14
|
Citations by publishers
|
5
10
15
20
25
|
|
|
American Chemical Society (ACS)
21 publications, 34.43%
|
|
|
Wiley
13 publications, 21.31%
|
|
|
Royal Society of Chemistry (RSC)
11 publications, 18.03%
|
|
|
Elsevier
10 publications, 16.39%
|
|
|
Walter de Gruyter
2 publications, 3.28%
|
|
|
Pleiades Publishing
1 publication, 1.64%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 1.64%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.64%
|
|
|
5
10
15
20
25
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[4,9,11,6,9,3,4,2,2,2,0,3,4,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["6.56","14.75","18.03","9.84","14.75","4.92","6.56","3.28","3.28","3.28",0,"4.92","6.56","1.64","1.64"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organometallics","Journal of the American Chemical Society","Dalton Transactions","Coordination Chemistry Reviews","Inorganic Chemistry Frontiers","Journal of Organometallic Chemistry","Chemical Communications","Inorganic Chemistry","Russian Journal of Inorganic Chemistry","Zeitschrift fur Kristallographie - Crystalline Materials","Molecules","Tetrahedron","Journal of Catalysis","Catalysis Communications","Polyhedron","Applied Catalysis A: General","Advanced Synthesis and Catalysis","Angewandte Chemie - International Edition","Angewandte Chemie","Applied Organometallic Chemistry","ChemCatChem","Organic Letters","Journal of Physical Chemistry A","ACS Catalysis","Green Chemistry","Annual Reports Section B (Organic Chemistry)","Chemical Science","New Journal of Chemistry","Zeitschrift fur Anorganische und Allgemeine Chemie"],"ids":[1409,4813,8473,13437,8397,11834,9073,24714,426,22111,1770,3439,20883,23806,21269,10438,3906,19215,25450,11683,10149,3315,15255,4873,1017,25522,9646,1404,18677],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[14,3,3,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[22.95,4.92,4.92,3.28,3.28,3.28,3.28,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64,1.64],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Elsevier","Walter de Gruyter","Pleiades Publishing","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,123,17,4,101,202,9422],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[21,13,11,10,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[34.43,21.31,18.03,16.39,3.28,1.64,1.64,1.64],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,1,0,0,0,0,0,1,0,0,0,2,0,0],"percentage":["0","1.64","1.64","0","0","0","0","0","1.64","0","0","0","3.28","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,1,0,2,1,0,0,0,1,0,0,0,1,0],"percentage":["0","1.64","1.64","0","3.28","1.64","0","0","0","1.64","0","0","0","1.64","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[4,6,9,4,4,2,3,1,1,1,0,1,2,0,1],"percentage":["6.56","9.84","14.75","6.56","6.56","3.28","4.92","1.64","1.64","1.64","0","1.64","3.28","0","1.64"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,0,2,3,0,1,1,0,0,0,2,0,0,0],"percentage":["0","1.64","0","3.28","4.92","0","1.64","1.64","0","0","0","3.28","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,1,0,0,0,1,0,0],"percentage":["0","0","0","0","0","0","0","0","1.64","0","0","0","1.64","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,1,0,0,0,0,0,0,1,0,0],"percentage":["0","0","0","0","0","1.64","0","0","0","0","0","0","1.64","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[3,6,5,2,3,2,1,1,0,1,0,1,0,0,0],"percentage":["4.92","9.84","8.2","3.28","4.92","3.28","1.64","1.64","0","1.64","0","1.64","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,2,5,2,3,0,2,0,1,1,0,0,2,1,1],"percentage":["1.64","3.28","8.2","3.28","4.92","0","3.28","0","1.64","1.64","0","0","3.28","1.64","1.64"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,1,1,2,3,0,1,1,0,0,0,2,0,0,0],"percentage":["0","1.64","1.64","3.28","4.92","0","1.64","1.64","0","0","0","3.28","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Rosen E. L. et al. Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes // Organometallics. 2009. Vol. 29. No. 1. pp. 250-256.
GOST all authors (up to 50)
Copy
Rosen E. L., Sung D. H., Chen Z., LYNCH V., Bielawski C. W. Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes // Organometallics. 2009. Vol. 29. No. 1. pp. 250-256.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om9008718
UR - https://doi.org/10.1021/om9008718
TI - Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes
T2 - Organometallics
AU - Rosen, Evelyn L
AU - Sung, Daphne H
AU - Chen, Zheng
AU - LYNCH, VINCENT
AU - Bielawski, Christopher W.
PY - 2009
DA - 2009/11/06 00:00:00
PB - American Chemical Society (ACS)
SP - 250-256
IS - 1
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex
Copy
@article{2009_Rosen,
author = {Evelyn L Rosen and Daphne H Sung and Zheng Chen and VINCENT LYNCH and Christopher W. Bielawski},
title = {Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes},
journal = {Organometallics},
year = {2009},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/om9008718},
number = {1},
pages = {250--256},
doi = {10.1021/om9008718}
}
Cite this
MLA
Copy
Rosen, Evelyn L., et al. “Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes.” Organometallics, vol. 29, no. 1, Nov. 2009, pp. 250-256. https://doi.org/10.1021/om9008718.