Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes
Publication type: Journal Article
Publication date: 2010-04-12
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Unsymmetrical NCS-pincer ligands of a new type, namely, m-(diphenylthiophosphoryloxy)benzaldimines 3 (1-[Ph2P(S)O]-3-[CH═NR]-C6H4, R = OMe (3a), Ph (3b), tBu (3c)), were obtained in two steps starting from commercially available 3-hydroxybenzaldehyde. These ligands easily underwent cyclopalladation at the C-2 position of the central benzene ring in the reaction with PdCl2(PhCN)2 in benzene or benzene−methanol solutions to afford the corresponding hybrid pincer complexes 4a−c with five- and six-membered fused metallacycles in moderate to good yields. The same reaction in dichloromethane followed by treatment with alcohol resulted in unexpected formation of the related NCO-palladacycles 5a,b, along with the above NCS-complexes. Complexes 5 present the products of formal oxidation of the P═S group in the starting ligand, which apparently proceeds in the metal ion coordination sphere. Realization of κ3-NCS and κ3-NCO coordination in 4a−c and 5a,b, respectively, was unambiguously confirmed by X-ray diffraction...
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54
Total citations:
54
Citations from 2024:
1
(1.85%)
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GOST
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Kozlov V. A. et al. Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes // Organometallics. 2010. Vol. 29. No. 9. pp. 2054-2062.
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Kozlov V. A., V. Aleksanyan D., Nelyubina Yu. V., Lyssenko K. A., Vasilev A. A., Petrovskii P., Odinets I. L. Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes // Organometallics. 2010. Vol. 29. No. 9. pp. 2054-2062.
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TY - JOUR
DO - 10.1021/om9009894
UR - https://doi.org/10.1021/om9009894
TI - Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes
T2 - Organometallics
AU - Kozlov, V. A.
AU - V. Aleksanyan, Diana
AU - Nelyubina, Yu V
AU - Lyssenko, Konstantin A.
AU - Vasilev, A. A.
AU - Petrovskii, P.V
AU - Odinets, I. L.
PY - 2010
DA - 2010/04/12
PB - American Chemical Society (ACS)
SP - 2054-2062
IS - 9
VL - 29
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2010_Kozlov,
author = {V. A. Kozlov and Diana V. Aleksanyan and Yu V Nelyubina and Konstantin A. Lyssenko and A. A. Vasilev and P.V Petrovskii and I. L. Odinets},
title = {Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes},
journal = {Organometallics},
year = {2010},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/om9009894},
number = {9},
pages = {2054--2062},
doi = {10.1021/om9009894}
}
Cite this
MLA
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Kozlov, V. A., et al. “Cyclopalladation of meta-(Diphenylthiophosphoryloxy)benzaldimines: NCS and Unexpected NCO 5,6-Membered Pincer Palladium Complexes.” Organometallics, vol. 29, no. 9, Apr. 2010, pp. 2054-2062. https://doi.org/10.1021/om9009894.
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