A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand
Publication type: Journal Article
Publication date: 1996-05-14
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The new ferrocene-based P,S-chiral auxiliary 1, derived from thioglucose, has been prepared and used in the palladium-catalyzed enantioselective allylic alkylation reaction. The X-ray structure of the allyl cationic complex [Pd(η3-PhCHCHCHPh)(1)]CF3SO3 (2) reveals a markedly rotated 1,3-diphenylallyl ligand such that the terminal allyl carbon C(3), trans to the phosphorus donor, is ca. 0.85(3) A below the coordination plane. This distortion is pertinent to the Pd(0) transition state complex expected in the allylic alkylation reaction.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
16
|
|
|
Organometallics
16 publications, 16.16%
|
|
|
Journal of Organometallic Chemistry
7 publications, 7.07%
|
|
|
Inorganica Chimica Acta
6 publications, 6.06%
|
|
|
Journal of Organic Chemistry
5 publications, 5.05%
|
|
|
Chemical Reviews
5 publications, 5.05%
|
|
|
Coordination Chemistry Reviews
5 publications, 5.05%
|
|
|
Tetrahedron Asymmetry
5 publications, 5.05%
|
|
|
Inorganic Chemistry
4 publications, 4.04%
|
|
|
European Journal of Inorganic Chemistry
4 publications, 4.04%
|
|
|
Organic Letters
3 publications, 3.03%
|
|
|
European Journal of Organic Chemistry
3 publications, 3.03%
|
|
|
Chemical Communications
3 publications, 3.03%
|
|
|
Organic and Biomolecular Chemistry
3 publications, 3.03%
|
|
|
Journal of the American Chemical Society
2 publications, 2.02%
|
|
|
Tetrahedron
2 publications, 2.02%
|
|
|
Chirality
2 publications, 2.02%
|
|
|
Journal of Peptide Science
2 publications, 2.02%
|
|
|
Comptes Rendus Chimie
1 publication, 1.01%
|
|
|
Carbohydrate Research
1 publication, 1.01%
|
|
|
Chemistry - A European Journal
1 publication, 1.01%
|
|
|
Magnetic Resonance in Chemistry
1 publication, 1.01%
|
|
|
Israel Journal of Chemistry
1 publication, 1.01%
|
|
|
Advanced Synthesis and Catalysis
1 publication, 1.01%
|
|
|
Applied Organometallic Chemistry
1 publication, 1.01%
|
|
|
Journal of Combinatorial Chemistry
1 publication, 1.01%
|
|
|
ACS Catalysis
1 publication, 1.01%
|
|
|
Annual Reports Section A (Inorganic Chemistry)
1 publication, 1.01%
|
|
|
Journal of Coordination Chemistry
1 publication, 1.01%
|
|
|
Heterocycles
1 publication, 1.01%
|
|
|
2
4
6
8
10
12
14
16
|
Publishers
|
5
10
15
20
25
30
35
40
|
|
|
American Chemical Society (ACS)
37 publications, 37.37%
|
|
|
Elsevier
28 publications, 28.28%
|
|
|
Wiley
17 publications, 17.17%
|
|
|
Royal Society of Chemistry (RSC)
7 publications, 7.07%
|
|
|
Georg Thieme Verlag KG
2 publications, 2.02%
|
|
|
Taylor & Francis
1 publication, 1.01%
|
|
|
The Japan Institute of Heterocyclic Chemistry
1 publication, 1.01%
|
|
|
Walter de Gruyter
1 publication, 1.01%
|
|
|
Proceedings of the National Academy of Sciences (PNAS)
1 publication, 1.01%
|
|
|
5
10
15
20
25
30
35
40
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
99
Total citations:
99
Citations from 2025:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Albinati A., Pregosin P. S., Wick K. A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand // Organometallics. 1996. Vol. 15. No. 10. pp. 2419-2421.
GOST all authors (up to 50)
Copy
Albinati A., Pregosin P. S., Wick K. A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand // Organometallics. 1996. Vol. 15. No. 10. pp. 2419-2421.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om950983m
UR - https://doi.org/10.1021/om950983m
TI - A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand
T2 - Organometallics
AU - Albinati, Alberto
AU - Pregosin, Paul S.
AU - Wick, Karin
PY - 1996
DA - 1996/05/14
PB - American Chemical Society (ACS)
SP - 2419-2421
IS - 10
VL - 15
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1996_Albinati,
author = {Alberto Albinati and Paul S. Pregosin and Karin Wick},
title = {A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand},
journal = {Organometallics},
year = {1996},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/om950983m},
number = {10},
pages = {2419--2421},
doi = {10.1021/om950983m}
}
Cite this
MLA
Copy
Albinati, Alberto, et al. “A New P,S-Chiral Auxiliary Derived from Thioglucose. X-ray Structure of a Palladium 1,3-Diphenylallyl Complex with a Strongly Rotated Allyl Ligand.” Organometallics, vol. 15, no. 10, May. 1996, pp. 2419-2421. https://doi.org/10.1021/om950983m.