Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands
1
Department of Chemistry, Moscow University, 119899 Moscow, Russia
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Publication type: Journal Article
Publication date: 1997-02-01
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Distannylated bis(cyclopentadienyl) and bis(indenyl) ligands react with ZrCl4 and HfCl4 to give the corresponding ansa-metallocenes in high yield. It was shown that the racemic forms of ansa-metallocenes could be prepared from the racemic forms of starting dielement-substituted bis(cyclopentadienyl) ligands.
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Nifant'ev I. E., Ivchenko P. V. Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands // Organometallics. 1997. Vol. 16. No. 4. pp. 713-715.
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Nifant'ev I. E., Ivchenko P. V. Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands // Organometallics. 1997. Vol. 16. No. 4. pp. 713-715.
Cite this
RIS
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TY - JOUR
DO - 10.1021/om960435o
UR - https://doi.org/10.1021/om960435o
TI - Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands
T2 - Organometallics
AU - Nifant'ev, Ilya E.
AU - Ivchenko, Pavel V
PY - 1997
DA - 1997/02/01
PB - American Chemical Society (ACS)
SP - 713-715
IS - 4
VL - 16
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
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@article{1997_Nifant'ev,
author = {Ilya E. Nifant'ev and Pavel V Ivchenko},
title = {Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands},
journal = {Organometallics},
year = {1997},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om960435o},
number = {4},
pages = {713--715},
doi = {10.1021/om960435o}
}
Cite this
MLA
Copy
Nifant'ev, Ilya E., and Pavel V Ivchenko. “Synthesis of Zirconium and Hafnium ansa-Metallocenes via Transmetalation of Dielement-Substituted Bis(cyclopentadienyl) and Bis(indenyl) Ligands.” Organometallics, vol. 16, no. 4, Feb. 1997, pp. 713-715. https://doi.org/10.1021/om960435o.
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