Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds
Alexander Z. Voskoboynikov
1
,
Inna N Parshina
1
,
Alla K. Shestakova
1
,
Kim P. Butin
1
,
Judith A. K. Howard
1
Publication type: Journal Article
Publication date: 1997-09-01
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of lanthanide and yttrium hydrocarbyls {Cp*2Ln(μ-Me)}2 (Cp* = tBuC5H4 (Cp‘), Ln = Y (1), Tb (2), Yb (3), Lu (4); Cp* = Me3SiC5H4 (Cp‘‘), Ln = Lu (5)), one of which, 2, has been characterized by X-ray crystal analysis, with various organosilicon, -germanium, and -tin hydrides (as well as some organoaluminum and -gallium hydrides) in hydrocarbon solution was found to yield the corresponding unsolvated dimeric lanthanide and yttrium hydrides {Cp*2Ln(μ-H)}2 rather than compounds with lanthanide−element (Si, Ge, Sn) bonding. Thus, the reaction involves hydride transfer to Ln rather than the silyl transfer studied earlier for pentamethylcyclopentadienyllanthanide hydrocarbyls. Dimeric compounds Cp*2Ln(μ-H)(μ-Me)LnCp*2 with different bridging ligands were isolated; they are intermediates in this reaction. Dimeric lanthanide and yttrium hydrides catalyze the H/D exchange in silanes. This catalytic reaction is most correctly described by a mechanism involving nucleophilic substitution at the silicon a...
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81
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81
Citations from 2024:
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(2.46%)
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GOST
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Voskoboynikov A. Z. et al. Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds // Organometallics. 1997. Vol. 16. No. 19. pp. 4041-4055.
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Voskoboynikov A. Z., Parshina I. N., Shestakova A. K., Butin K. P., Beletskaya I. P., Kuz'mina L. G., Howard J. A. K. Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds // Organometallics. 1997. Vol. 16. No. 19. pp. 4041-4055.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om970363g
UR - https://doi.org/10.1021/om970363g
TI - Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds
T2 - Organometallics
AU - Voskoboynikov, Alexander Z.
AU - Parshina, Inna N
AU - Shestakova, Alla K.
AU - Butin, Kim P.
AU - Beletskaya, Irina P.
AU - Kuz'mina, Lyudmila G.
AU - Howard, Judith A. K.
PY - 1997
DA - 1997/09/01
PB - American Chemical Society (ACS)
SP - 4041-4055
IS - 19
VL - 16
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1997_Voskoboynikov,
author = {Alexander Z. Voskoboynikov and Inna N Parshina and Alla K. Shestakova and Kim P. Butin and Irina P. Beletskaya and Lyudmila G. Kuz'mina and Judith A. K. Howard},
title = {Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds},
journal = {Organometallics},
year = {1997},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/om970363g},
number = {19},
pages = {4041--4055},
doi = {10.1021/om970363g}
}
Cite this
MLA
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Voskoboynikov, Alexander Z., et al. “Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds.” Organometallics, vol. 16, no. 19, Sep. 1997, pp. 4041-4055. https://doi.org/10.1021/om970363g.
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