Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions
1
Penn Specialty Chemicals, Inc., 3324 Chelsea Avenue, Memphis, Tennessee 38108, U.S.A.
|
Publication type: Journal Article
Publication date: 2006-12-06
scimago Q1
wos Q1
SJR: 0.865
CiteScore: 5.4
Impact factor: 3.5
ISSN: 10836160, 1520586X
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
2-Methyltetrahydrofuran (MeTHF) is a commercially available solvent that is produced from renewable resources. The properties of MeTHF place it between tetrahydrofuran (THF) and diethyl ether in solvent polarity and Lewis base strength. In many cases, MeTHF can replace THF in organometallic reactions. The formation and reaction of Grignard reagents in MeTHF and THF are similar. MeTHF can be used as a solvent for low-temperature lithiation, for lithium aluminum hydride reductions, for the Reformatsky reaction, and for metal-catalyzed coupling reactions. MeTHF is also a good substitute for dichloromethane in biphasic reactions.
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421
Total citations:
421
Citations from 2025:
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(5.48%)
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GOST
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Aycock D. F. Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions // Organic Process Research and Development. 2006. Vol. 11. No. 1. pp. 156-159.
GOST all authors (up to 50)
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Aycock D. F. Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions // Organic Process Research and Development. 2006. Vol. 11. No. 1. pp. 156-159.
Cite this
RIS
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TY - JOUR
DO - 10.1021/op060155c
UR - https://doi.org/10.1021/op060155c
TI - Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions
T2 - Organic Process Research and Development
AU - Aycock, David F
PY - 2006
DA - 2006/12/06
PB - American Chemical Society (ACS)
SP - 156-159
IS - 1
VL - 11
SN - 1083-6160
SN - 1520-586X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Aycock,
author = {David F Aycock},
title = {Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions},
journal = {Organic Process Research and Development},
year = {2006},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/op060155c},
number = {1},
pages = {156--159},
doi = {10.1021/op060155c}
}
Cite this
MLA
Copy
Aycock, David F.. “Solvent Applications of 2-Methyltetrahydrofuran in Organometallic and Biphasic Reactions.” Organic Process Research and Development, vol. 11, no. 1, Dec. 2006, pp. 156-159. https://doi.org/10.1021/op060155c.