Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate
Jeffrey C. Bryan
1
,
L\sgmaeligtitia H Delmau
1
,
Benjamin P Hay
2
,
John B. Nicholas
2
,
Lillian M Rogers
3
,
Robin D. Rogers
3
,
Bruce A Moyer
1
Publication type: Journal Article
Publication date: 1999-01-01
scimago Q3
wos Q2
SJR: 0.341
CiteScore: 4.3
Impact factor: 2.2
ISSN: 10400400, 15729001
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
Extraction experiments show that 2-benzylphenol is an efficient and selective extractant for cesium. The structures of cesium and potassium 2-benzylphenolate were determined. Both structures also contain 2-benzylphenol, which ligates the cation, through its phenolic oxygen atom and the benzyl ring. The phenolate oxygen atom does not directly contact the cation in either structure, but is a hydrogen-bond acceptor to the 2-benzylphenol ligands, forming a supramolecular assembly. For comparison to the bound ligands, the structure of 2-benzylphenol was also determined. Molecular mechanics and ab initio molecular orbital theory are used to rationalize several aspects of Cs/Na selectivity.
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Bryan J. C. et al. Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate // Structural Chemistry. 1999. Vol. 10. No. 3. pp. 187-203.
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Bryan J. C., Delmau L. H., Hay B. P., Nicholas J. B., Rogers L. M., Rogers R. D., Moyer B. A. Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate // Structural Chemistry. 1999. Vol. 10. No. 3. pp. 187-203.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1023/a:1021884429538
UR - https://doi.org/10.1023/a:1021884429538
TI - Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate
T2 - Structural Chemistry
AU - Bryan, Jeffrey C.
AU - Delmau, L\sgmaeligtitia H
AU - Hay, Benjamin P
AU - Nicholas, John B.
AU - Rogers, Lillian M
AU - Rogers, Robin D.
AU - Moyer, Bruce A
PY - 1999
DA - 1999/01/01
PB - Springer Nature
SP - 187-203
IS - 3
VL - 10
SN - 1040-0400
SN - 1572-9001
ER -
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BibTex (up to 50 authors)
Copy
@article{1999_Bryan,
author = {Jeffrey C. Bryan and L\sgmaeligtitia H Delmau and Benjamin P Hay and John B. Nicholas and Lillian M Rogers and Robin D. Rogers and Bruce A Moyer},
title = {Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate},
journal = {Structural Chemistry},
year = {1999},
volume = {10},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1023/a:1021884429538},
number = {3},
pages = {187--203},
doi = {10.1023/a:1021884429538}
}
Cite this
MLA
Copy
Bryan, Jeffrey C., et al. “Cesium Recognition by Supramolecular Assemblies of 2-Benzylphenol and 2-Benzylphenolate.” Structural Chemistry, vol. 10, no. 3, Jan. 1999, pp. 187-203. https://doi.org/10.1023/a:1021884429538.