Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis
Publication type: Journal Article
Publication date: 2001-01-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The structure and activity of C–Cl bond metathesis catalysts containing CuCl2and triethylenetetramine (TETA) supported on silica were studied. The catalysts were found to contain ∼40% Cu(II) as paramagnetic complexes of the composition Cu(TETA)2Cl2and diamagnetic binuclear or polynuclear copper complexes, which are undetectable by EPR spectroscopy. The catalytic activity of the test systems in the radical reaction of C–Cl bond metathesis in the CCl4–C10H22system was maximum at a Cu(II) concentration of ∼0.5 wt % on the support. A kinetic scheme was proposed, which suggests that only mononuclear copper complexes participate at the stage of radical generation, whereas termination can also occur on binuclear or polynuclear complexes.
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Kharitonov D. N. et al. Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis // Kinetics and Catalysis. 2001. Vol. 42. No. 5. pp. 673-678.
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Kharitonov D. N., Golubeva E. N., Pergushov V., Kokorin A. I., Smirnov V. V. Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis // Kinetics and Catalysis. 2001. Vol. 42. No. 5. pp. 673-678.
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TY - JOUR
DO - 10.1023/A:1012375731860
UR - https://doi.org/10.1023/A:1012375731860
TI - Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis
T2 - Kinetics and Catalysis
AU - Kharitonov, D N
AU - Golubeva, E. N.
AU - Pergushov, V.I.
AU - Kokorin, A I
AU - Smirnov, V. V.
PY - 2001
DA - 2001/01/01
PB - Pleiades Publishing
SP - 673-678
IS - 5
VL - 42
SN - 0023-1584
SN - 1608-3210
ER -
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@article{2001_Kharitonov,
author = {D N Kharitonov and E. N. Golubeva and V.I. Pergushov and A I Kokorin and V. V. Smirnov},
title = {Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis},
journal = {Kinetics and Catalysis},
year = {2001},
volume = {42},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1023/A:1012375731860},
number = {5},
pages = {673--678},
doi = {10.1023/A:1012375731860}
}
Cite this
MLA
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Kharitonov, D. N., et al. “Immobilized complexes of copper(II) chloride with triethylenetetramine as catalysts for the reaction of C-Cl bond metathesis.” Kinetics and Catalysis, vol. 42, no. 5, Jan. 2001, pp. 673-678. https://doi.org/10.1023/A:1012375731860.
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