Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2
S.V. Rusakov
1
,
L M Khalilov
1
,
L V Parfenova
1
,
A G Ibragimov
1
,
O.A. Ponomarev
1
,
U M Dzhemilev
1
Publication type: Journal Article
Publication date: 2001-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Cyclometallation of olefins with AlEt3 in the presence of Cp2ZrCl2 affording five-membered monosubstituted cyclic organoaluminum compounds, was studied by the semiempirical quantum-chemical PM3 method. The proposed model of catalytic cycloalumination of styrene catalyzed by Cp2ZrCl2 is in a good accordance with experimental data obtained by dynamic NMR spectroscopy.
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Total citations:
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Citations from 2024:
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GOST
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Rusakov S. et al. Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2 // Russian Chemical Bulletin. 2001. Vol. 50. No. 12. pp. 2336-2345.
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Rusakov S., Khalilov L. M., Parfenova L. V., Ibragimov A. G., Ponomarev O., Dzhemilev U. M. Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2 // Russian Chemical Bulletin. 2001. Vol. 50. No. 12. pp. 2336-2345.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1023/A:1015019109791
UR - https://doi.org/10.1023/A:1015019109791
TI - Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2
T2 - Russian Chemical Bulletin
AU - Rusakov, S.V.
AU - Khalilov, L M
AU - Parfenova, L V
AU - Ibragimov, A G
AU - Ponomarev, O.A.
AU - Dzhemilev, U M
PY - 2001
DA - 2001/01/01
PB - Springer Nature
SP - 2336-2345
IS - 12
VL - 50
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2001_Rusakov,
author = {S.V. Rusakov and L M Khalilov and L V Parfenova and A G Ibragimov and O.A. Ponomarev and U M Dzhemilev},
title = {Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2},
journal = {Russian Chemical Bulletin},
year = {2001},
volume = {50},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1023/A:1015019109791},
number = {12},
pages = {2336--2345},
doi = {10.1023/A:1015019109791}
}
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MLA
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Rusakov, S.V., et al. “Synthesis and transformations of metallacycles. 27. Quantum-chemical study of the mechanism of styrene catalytic cyclometallation with triethylaluminum in the presence of Cp2ZrCl2.” Russian Chemical Bulletin, vol. 50, no. 12, Jan. 2001, pp. 2336-2345. https://doi.org/10.1023/A:1015019109791.
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