Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis
Publication type: Journal Article
Publication date: 2002-12-28
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The chloride complexes of copper(II) (catalysts or catalyst precursors for various reactions of halogenated hydrocarbons) were characterized using electron, EPR, and EXAFS spectroscopy. It was found that chlorocuprates occur as mononuclear ([CuCl4]2–), binuclear ([Cu2Cl6]2–), and, probably, polynuclear species in chlorobenzene solutions. The Cu–Cl bond length in [CuCl4]2– is 2.25 ± 0.2 Å, which is close to the same values for crystalline tetrachlorocuprates. It was assumed that the chloride complexes of copper with counterions occur as globules in chlorobenzene.
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Golubeva E. N. et al. Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis // Kinetics and Catalysis. 2002. Vol. 43. No. 3. pp. 408-411.
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Golubeva E. N., Kokorin A. I., Kochubei D., Pergushov V., Kriventsov V. Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis // Kinetics and Catalysis. 2002. Vol. 43. No. 3. pp. 408-411.
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RIS
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TY - JOUR
DO - 10.1023/A:1016018204168
UR - https://doi.org/10.1023/A:1016018204168
TI - Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis
T2 - Kinetics and Catalysis
AU - Golubeva, E. N.
AU - Kokorin, A I
AU - Kochubei, D.I.
AU - Pergushov, V.I.
AU - Kriventsov, V.V.
PY - 2002
DA - 2002/12/28
PB - Pleiades Publishing
SP - 408-411
IS - 3
VL - 43
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (up to 50 authors)
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@article{2002_Golubeva,
author = {E. N. Golubeva and A I Kokorin and D.I. Kochubei and V.I. Pergushov and V.V. Kriventsov},
title = {Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis},
journal = {Kinetics and Catalysis},
year = {2002},
volume = {43},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1023/A:1016018204168},
number = {3},
pages = {408--411},
doi = {10.1023/A:1016018204168}
}
Cite this
MLA
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Golubeva, E. N., et al. “Structure and Composition of the Anionic Chloride Complexes of Copper(II) as the Precursors of Catalysts for C–Cl Bond Metathesis.” Kinetics and Catalysis, vol. 43, no. 3, Dec. 2002, pp. 408-411. https://doi.org/10.1023/A:1016018204168.
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