Formation of cobalt(III) cations with semiquinonediimine ligands
I.G. Fomina
1
,
A. A. Sidorov
1
,
G.G. Aleksandrov
1
,
V. N. Ikorskii
2
,
V. M. Novotortsev
1
,
S.E. Nefedov
1
,
Publication type: Journal Article
Publication date: 2002-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The reactions of polynuclear cobalt(ii) trimethylacetates [Co(OH) n (OOCCMe3)2–n ] x , Co6(μ3-OH)2(OOCCMe3)10(HOOCCMe3)4, or Co4(μ3-OH)2(OOCCMe3)6(HOEt)6 with an excess of N-phenyl-o-phenylenediamine (1) in toluene followed by treatment with atmospheric oxygen afforded the diamagnetic complex [Co{η2-(NPh)(NH)C6H4}2{η1-(NH2)C6H4(NPhH)}]+(Me3CCOO...H...OOCCMe3)– (3), whose cation contains the CoIII atom. The reaction of Co4(μ3-OH)2(OOCCMe3)6(HOEt)6 with a deficient amount of diamine 1 in acetonitrile under an argon atmosphere gave rise to the antiferromagnetic ionic complex [Co{η2-(NPh)(NH)C6H4}2MeCN]+[Co2(μ2,η2-OOCCMe3)(μ2-OOCCMe3)2(η2-OOCCMe3)2]–·2MeCN (4), whose cation is an isoelectronic analog of the cation in complex 3. The structures of the new compounds were established by X-ray diffraction analysis.
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Fomina I. et al. Formation of cobalt(III) cations with semiquinonediimine ligands // Russian Chemical Bulletin. 2002. Vol. 51. No. 8. pp. 1581-1587.
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Fomina I., Sidorov A. A., Aleksandrov G., Ikorskii V. N., Novotortsev V. M., Nefedov S., Eremenko I. L. Formation of cobalt(III) cations with semiquinonediimine ligands // Russian Chemical Bulletin. 2002. Vol. 51. No. 8. pp. 1581-1587.
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RIS
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TY - JOUR
DO - 10.1023/A:1020948014647
UR - https://doi.org/10.1023/A:1020948014647
TI - Formation of cobalt(III) cations with semiquinonediimine ligands
T2 - Russian Chemical Bulletin
AU - Fomina, I.G.
AU - Sidorov, A. A.
AU - Aleksandrov, G.G.
AU - Ikorskii, V. N.
AU - Novotortsev, V. M.
AU - Nefedov, S.E.
AU - Eremenko, I. L.
PY - 2002
DA - 2002/01/01
PB - Springer Nature
SP - 1581-1587
IS - 8
VL - 51
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2002_Fomina,
author = {I.G. Fomina and A. A. Sidorov and G.G. Aleksandrov and V. N. Ikorskii and V. M. Novotortsev and S.E. Nefedov and I. L. Eremenko},
title = {Formation of cobalt(III) cations with semiquinonediimine ligands},
journal = {Russian Chemical Bulletin},
year = {2002},
volume = {51},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1023/A:1020948014647},
number = {8},
pages = {1581--1587},
doi = {10.1023/A:1020948014647}
}
Cite this
MLA
Copy
Fomina, I.G., et al. “Formation of cobalt(III) cations with semiquinonediimine ligands.” Russian Chemical Bulletin, vol. 51, no. 8, Jan. 2002, pp. 1581-1587. https://doi.org/10.1023/A:1020948014647.