Kinetics and Catalysis

, том 44 , издание 4 , страницы 513-517

Dimerization of Chlorocuprates in Weakly Polar Solvents

Тип публикации: Journal Article

Дата публикации: 2003-09-16

Pleiades Publishing

Kinetics and Catalysis

scimago Q3

wos Q4

БС2

SJR: 0.260

CiteScore: 1.9

Impact factor: 1.4

ISSN: 00231584, 16083210

DOI: 10.1023/A:1025138000121

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Краткое описание

The solutions of CuCl2 and tributylbenzylammonium chloride in chlorobenzene, which are used as catalysts for a number of processes with the participation of halogenated hydrocarbons, were studied by electronic spectroscopy in visible and UV regions. It was found that copper(II) ions occurred as two anionic chlorocuprate species (CuCl2- 4 and Cu2Cl2- 6), which were in equilibrium, in solutions over wide ranges of concentrations and temperatures. The individual spectra of the two above chlorocuprate species were distinguished. The thermodynamic parameters of the equilibrium 2CuCl2- 4 ⇄ Cu2Cl2- 6 + 2Cl– were calculated.

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Московский государственный университет имени М.В. Ломоносова

Области научных интересов

Квантовая химия

Молекулярная динамика

Спектроскопия

Химия полимеров

ЭПР-спектроскопия

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Kinetics and Catalysis	Kinetics and Catalysis, 4, 36.36% Kinetics and Catalysis 4 публикации, 36.36%
Journal of Physical Chemistry A	Journal of Physical Chemistry A, 2, 18.18% Journal of Physical Chemistry A 2 публикации, 18.18%
High Energy Chemistry	High Energy Chemistry, 1, 9.09% High Energy Chemistry 1 публикация, 9.09%
Russian Journal of Physical Chemistry B	Russian Journal of Physical Chemistry B, 1, 9.09% Russian Journal of Physical Chemistry B 1 публикация, 9.09%
Journal of Natural Gas Chemistry	Journal of Natural Gas Chemistry, 1, 9.09% Journal of Natural Gas Chemistry 1 публикация, 9.09%
Inorganic Chemistry	Inorganic Chemistry, 1, 9.09% Inorganic Chemistry 1 публикация, 9.09%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 9.09% Chemistry - A European Journal 1 публикация, 9.09%
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Kharitonov D. N., Golubeva E. N. Dimerization of Chlorocuprates in Weakly Polar Solvents // Kinetics and Catalysis. 2003. Vol. 44. No. 4. pp. 513-517.

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Kharitonov D. N., Golubeva E. N. Dimerization of Chlorocuprates in Weakly Polar Solvents // Kinetics and Catalysis. 2003. Vol. 44. No. 4. pp. 513-517.

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TY - JOUR

DO - 10.1023/A:1025138000121

UR - https://doi.org/10.1023/A:1025138000121

TI - Dimerization of Chlorocuprates in Weakly Polar Solvents

T2 - Kinetics and Catalysis

AU - Kharitonov, D N

AU - Golubeva, E. N.

PY - 2003

DA - 2003/09/16

PB - Pleiades Publishing

SP - 513-517

IS - 4

VL - 44

SN - 0023-1584

SN - 1608-3210

ER -

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@article{2003_Kharitonov,

author = {D N Kharitonov and E. N. Golubeva},

title = {Dimerization of Chlorocuprates in Weakly Polar Solvents},

journal = {Kinetics and Catalysis},

year = {2003},

volume = {44},

publisher = {Pleiades Publishing},

month = {sep},

url = {https://doi.org/10.1023/A:1025138000121},

number = {4},

pages = {513--517},

doi = {10.1023/A:1025138000121}

}

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Kharitonov, D. N., and E. N. Golubeva. “Dimerization of Chlorocuprates in Weakly Polar Solvents.” Kinetics and Catalysis, vol. 44, no. 4, Sep. 2003, pp. 513-517. https://doi.org/10.1023/A:1025138000121.