Dimerization of Chlorocuprates in Weakly Polar Solvents
Publication type: Journal Article
Publication date: 2003-09-16
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The solutions of CuCl2 and tributylbenzylammonium chloride in chlorobenzene, which are used as catalysts for a number of processes with the participation of halogenated hydrocarbons, were studied by electronic spectroscopy in visible and UV regions. It was found that copper(II) ions occurred as two anionic chlorocuprate species (CuCl2- 4 and Cu2Cl2- 6), which were in equilibrium, in solutions over wide ranges of concentrations and temperatures. The individual spectra of the two above chlorocuprate species were distinguished. The thermodynamic parameters of the equilibrium 2CuCl2- 4 ⇄ Cu2Cl2- 6 + 2Cl– were calculated.
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GOST
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Kharitonov D. N., Golubeva E. N. Dimerization of Chlorocuprates in Weakly Polar Solvents // Kinetics and Catalysis. 2003. Vol. 44. No. 4. pp. 513-517.
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Kharitonov D. N., Golubeva E. N. Dimerization of Chlorocuprates in Weakly Polar Solvents // Kinetics and Catalysis. 2003. Vol. 44. No. 4. pp. 513-517.
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RIS
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TY - JOUR
DO - 10.1023/A:1025138000121
UR - https://doi.org/10.1023/A:1025138000121
TI - Dimerization of Chlorocuprates in Weakly Polar Solvents
T2 - Kinetics and Catalysis
AU - Kharitonov, D N
AU - Golubeva, E. N.
PY - 2003
DA - 2003/09/16
PB - Pleiades Publishing
SP - 513-517
IS - 4
VL - 44
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Kharitonov,
author = {D N Kharitonov and E. N. Golubeva},
title = {Dimerization of Chlorocuprates in Weakly Polar Solvents},
journal = {Kinetics and Catalysis},
year = {2003},
volume = {44},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1023/A:1025138000121},
number = {4},
pages = {513--517},
doi = {10.1023/A:1025138000121}
}
Cite this
MLA
Copy
Kharitonov, D. N., and E. N. Golubeva. “Dimerization of Chlorocuprates in Weakly Polar Solvents.” Kinetics and Catalysis, vol. 44, no. 4, Sep. 2003, pp. 513-517. https://doi.org/10.1023/A:1025138000121.
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