Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine
E V Pakhmutova
1
,
A.E. Malkov
1
,
T B Mikhailova
1
,
A. A. Sidorov
1
,
I.G. Fomina
1
,
G.G. Aleksandrov
1
,
V. M. Novotortsev
1
,
V. N. Ikorskii
2
,
Тип публикации: Journal Article
Дата публикации: 2003-10-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
The reactions of the polymeric complex [Co(OH)n(OOCCMe3)2–n ]x (1) with 2-amino-5-methylpyridine (L1) and 2,6-diaminopyridine (L2) under anaerobic conditions at the ratio M : L = 1 : 1 afforded the binuclear complexes Co2(μ-OOCCMe3)4[η-MeC5H3N(NH2)]2 (2) and Co2(μ-OOCCMe3)4[η-C5H3N(NH2)2]2 (3), respectively, with Chinese-lantern-like structures. The reaction of the tetranuclear cobalt(ii) complex Co4(μ3-OH)2(μ-OOCCMe3)4(η2-OOCCMe3)2(EtOH)6 (4) with 2,6-diaminopyridine under anaerobic conditions at the ratio M : L2 = 2 : 1 gave rise to the antiferromagnetic tetranuclear complex Co4(μ4-O)[μ-C5H3N(NH2)2]2(μ-OOCCMe3)4(η2-OOCCMe3)2 (5) with tetradentate-bridging coordination of the oxygen atom. The structures of the compounds synthesized were established by X-ray diffraction analysis.
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Pakhmutova E. V. et al. Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine // Russian Chemical Bulletin. 2003. Vol. 52. No. 10. pp. 2117-2124.
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Pakhmutova E. V., Malkov A., Mikhailova T. B., Sidorov A. A., Fomina I., Aleksandrov G., Novotortsev V. M., Ikorskii V. N., Eremenko I. L. Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine // Russian Chemical Bulletin. 2003. Vol. 52. No. 10. pp. 2117-2124.
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TY - JOUR
DO - 10.1023/B:RUCB.0000011866.57209.5b
UR - https://doi.org/10.1023/B:RUCB.0000011866.57209.5b
TI - Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine
T2 - Russian Chemical Bulletin
AU - Pakhmutova, E V
AU - Malkov, A.E.
AU - Mikhailova, T B
AU - Sidorov, A. A.
AU - Fomina, I.G.
AU - Aleksandrov, G.G.
AU - Novotortsev, V. M.
AU - Ikorskii, V. N.
AU - Eremenko, I. L.
PY - 2003
DA - 2003/10/01
PB - Springer Nature
SP - 2117-2124
IS - 10
VL - 52
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2003_Pakhmutova,
author = {E V Pakhmutova and A.E. Malkov and T B Mikhailova and A. A. Sidorov and I.G. Fomina and G.G. Aleksandrov and V. M. Novotortsev and V. N. Ikorskii and I. L. Eremenko},
title = {Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine},
journal = {Russian Chemical Bulletin},
year = {2003},
volume = {52},
publisher = {Springer Nature},
month = {oct},
url = {https://doi.org/10.1023/B:RUCB.0000011866.57209.5b},
number = {10},
pages = {2117--2124},
doi = {10.1023/B:RUCB.0000011866.57209.5b}
}
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Pakhmutova, E. V., et al. “Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine.” Russian Chemical Bulletin, vol. 52, no. 10, Oct. 2003, pp. 2117-2124. https://doi.org/10.1023/B:RUCB.0000011866.57209.5b.