Nature Energy, volume 5, issue 1, pages 35-49

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Khenkin M. V. ^{1, 2}

Katz Eugene R. ^{1, 3}

Abate Antonio ⁴

Bardizza Giorgio ⁵

Berry Joseph J ⁶

Brabec Christoph ^{7, 8}

Brunetti Francesca ⁹

Bulovic Vladimir ¹⁰

Burlingame Quinn ¹¹

Carlo Aldo di ⁹

Cheacharoen Rongrong ¹²

Cheng Yi-Bing ¹³

Colsmann Alexander ¹⁴

Cros Stephane ¹⁵

Domanski Konrad ¹⁶

Dusza Michał ¹⁷

Fell Christopher R. ¹⁸

Forrest Stephen R. ^{19, 20, 21}

Galagan Yulia ²²

Di Girolamo Diego ^{9, 23}

Grätzel Michael ²⁴

Hagfeldt Anders ²⁵

Von Hauff Elizabeth ²⁶

Hoppe Harald ²⁷

Kettle Jeff ²⁸

Köbler Hans ⁴

Leite Marina S ^{29, 30}

Liu Shengzhong ^{31, 32}

Loo Yueh-Lin ^{11, 33}

Luther Joseph M. ⁶

Ma Chang Qi ³⁴

Hannibal Madsen Morten ³⁵

Manceau Matthieu ¹⁵

Matheron Muriel ¹⁵

McGehee Michael ^{6, 36}

Meitzner Rico ²⁷

Nazeeruddin M. ³⁷

M. F. Nogueira Ana Margarida ³⁸

Odabaşı Çağla ³⁹

Osherov Anna ¹⁰

Park Nam-Gyu ⁴⁰

Reese Matthew O ⁶

De Rossi Francesca ^{9, 41}

Saliba Michael ^{42, 43}

Schubert Ulrich S. ^{27, 44}

Snaith Henry ⁴⁵

Stranks Samuel D. ⁴⁶

Tress Wolfgang ²⁵

Troshin Pavel A. ^{47, 48}

Turkovic Vida ³⁵

Veenstra Sjoerd ²²

Visoly-Fisher I ^{1, 3}

Walsh Aron ^{49, 50}

Watson Trystan M. ⁴¹

Xie Haibing ⁵¹

Yildirim Ramazan ³⁹

Zakeeruddin Shaik Mohammed ²⁴

Zhu Kai ⁶

Lira Cantú Mónica ⁵¹

Hide authors affiliations Show authors affiliations: 51 affiliations

Department of Solar Energy and Environmental Physics, Swiss Institute for Dryland Environmental and Energy Research, J. Blaustein Institutes for Desert Research, Ben-Gurion University of the Negev, Midreshet Ben-Gurion, Israel |

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, PVcomB, Berlin, Germany |

Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Be’er- Sheva, Israel |

⁴

Helmholtz-Zentrum Berlin Für Materialien Und Energie GmbH, Berlin, Germany |

⁵

European Commission, Joint Research Centre (JRC), Ispra, Italy |

⁶

National Renewable Energy Laboratory, Golden, USA |

⁷

Helmholtz Institute Erlangen-Nürnberg (HI-ErN), Forschungszentrum Jülich (FZJ), Erlangen, Germany |

⁸

Department of Materials Science and Engineering, Friedrich Alexander University Erlangen Nürnberg, Erlangen, Germany |

⁹

CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata, Rome, Italy |

¹⁰

Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, USA |

¹¹

Andlinger Center for Energy & The Environment, Princeton University, Princeton, USA |

¹²

Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok, Thailand |

¹³

State key laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China |

¹⁴

Light Technology Institute, Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany |

¹⁵

University of Grenoble Alpes, CEA, LITEN, INES, Le Bourget du Lac, France |

¹⁶

Fluxim AG, Winterthur, Switzerland |

¹⁷

Saule Technologies, Wroclaw Technology Park, Wroclaw, Poland |

¹⁸

CSIRO Energy, Mayfield West, Australia |

¹⁹

Department of Materials Science and Engineering, University Of Michigan, Ann Arbor, USA |

²⁰

Department of Physics, University of Michigan, Ann Arbor, USA |

²¹

Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, USA |

²²

TNO - Solliance, High Tech Campus, Eindhoven, The Netherlands |

²³

Department of Chemistry, University of Rome La Sapienza, Rome, Italy |

²⁴

Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland |

²⁵

Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland |

²⁶

Department of Physics and Astronomy, Vrije Universiteit Amsterdam, Amsterdam, the Netherlands |

²⁷

Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller University Jena, Jena, Germany |

²⁸

School of Electronic Engineering, Bangor University, Bangor, Gwynedd, UK |

²⁹

Department of Materials Science and Engineering, University of California, Davis, USA |

³⁰

Department of Materials Science and Engineering, Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, USA |

³¹

Key Laboratory for Advanced Energy Devices; Shaanxi Engineering Lab for Advanced Energy Technology; Institute for Advanced Energy Materials; School of Materials Science and Engineering, Shaanxi Normal University, Xi’an, China |

³²

Dalian National Laboratory for Clean Energy/Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China |

³³

Department of Chemical and Biological Engineering, Princeton University, Princeton, USA |

³⁴

Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS), Suzhou, China |

³⁵

SDU nanoSYD, Mads Clausen Institute, University of Southern Denmark, Sønderborg, Denmark |

³⁶

University of Colorado Boulder, Boulder, USA |

³⁷

Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Sion, Switzerland |

³⁸

Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas – UNICAMP, Campinas, Brazil |

³⁹

Department of Chemical Engineering, BoğaziÇi University, Bebek, Istanbul, Turkey |

⁴⁰

School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon, Korea |

⁴¹

SPECIFIC, College of Engineering, Swansea University, Bay Campus, Swansea, UK |

⁴²

IEK-5 Photovoltaik, Forschungszentrum Jülich GmbH, Jülich, Germany |

⁴³

Institute of Materials Science, Technical University of Darmstadt, Darmstadt, Germany |

⁴⁴

Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany |

⁴⁵

Clarendon Laboratory, University of Oxford, Oxford, UK |

⁴⁶

Cavendish laboratory, University of Cambridge, Cambridge, UK |

⁴⁷

Skolkovo Institute of Science and technology, Moscow, Russia |

⁴⁸

IPCP RAS, Chernogolovka, Russia |

⁴⁹

Department of materials, Imperial College London, London, UK |

⁵⁰

Department of Materials Science and Engineering, Yonsei University, Seoul, Korea |

⁵¹

Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Bellaterra, Spain |

Publication type: Journal Article

Publication date: 2020-01-22

Springer Nature

Journal: Nature Energy

Quartile SCImago

Quartile WOS

Impact factor: 56.7

ISSN: 20587546

DOI: 10.1038/s41560-019-0529-5

Copy DOI

Electronic, Optical and Magnetic Materials

Energy Engineering and Power Technology

Fuel Technology

Renewable Energy, Sustainability and the Environment

Abstract

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

By date By citations

Citations by journals

	5 10 15 20 25 30 35 40 45
Advanced Energy Materials	Advanced Energy Materials, 45, 5.7% Advanced Energy Materials 45 publications, 5.7%
Solar RRL	Solar RRL, 37, 4.68% Solar RRL 37 publications, 4.68%
ACS applied materials & interfaces	ACS applied materials & interfaces, 35, 4.43% ACS applied materials & interfaces 35 publications, 4.43%
ACS Energy Letters	ACS Energy Letters, 33, 4.18% ACS Energy Letters 33 publications, 4.18%
Advanced Materials	Advanced Materials, 27, 3.42% Advanced Materials 27 publications, 3.42%
Advanced Functional Materials	Advanced Functional Materials, 25, 3.16% Advanced Functional Materials 25 publications, 3.16%
Nature Energy	Nature Energy, 24, 3.04% Nature Energy 24 publications, 3.04%
Energy and Environmental Science	Energy and Environmental Science, 23, 2.91% Energy and Environmental Science 23 publications, 2.91%
Nano Energy	Nano Energy, 22, 2.78% Nano Energy 22 publications, 2.78%
ACS Applied Energy Materials	ACS Applied Energy Materials, 21, 2.66% ACS Applied Energy Materials 21 publications, 2.66%
Joule	Joule, 21, 2.66% Joule 21 publications, 2.66%
Science	Science, 18, 2.28% Science 18 publications, 2.28%
Energy Technology	Energy Technology, 18, 2.28% Energy Technology 18 publications, 2.28%
Sustainable Energy and Fuels	Sustainable Energy and Fuels, 14, 1.77% Sustainable Energy and Fuels 14 publications, 1.77%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 14, 1.77% Journal of Materials Chemistry A 14 publications, 1.77%
Nature Communications	Nature Communications, 13, 1.65% Nature Communications 13 publications, 1.65%
Journal of Materials Chemistry C	Journal of Materials Chemistry C, 13, 1.65% Journal of Materials Chemistry C 13 publications, 1.65%
Solar Energy	Solar Energy, 12, 1.52% Solar Energy 12 publications, 1.52%
Journal of Energy Chemistry	Journal of Energy Chemistry, 9, 1.14% Journal of Energy Chemistry 9 publications, 1.14%
Advanced Science	Advanced Science, 9, 1.14% Advanced Science 9 publications, 1.14%
Journal of Physical Chemistry Letters	Journal of Physical Chemistry Letters, 8, 1.01% Journal of Physical Chemistry Letters 8 publications, 1.01%
Energies	Energies, 8, 1.01% Energies 8 publications, 1.01%
Chemical Engineering Journal	Chemical Engineering Journal, 8, 1.01% Chemical Engineering Journal 8 publications, 1.01%
Nature	Nature, 7, 0.89% Nature 7 publications, 0.89%
Matter	Matter, 7, 0.89% Matter 7 publications, 0.89%
Solar Energy Materials and Solar Cells	Solar Energy Materials and Solar Cells, 7, 0.89% Solar Energy Materials and Solar Cells 7 publications, 0.89%
Small Methods	Small Methods, 7, 0.89% Small Methods 7 publications, 0.89%
Angewandte Chemie	Angewandte Chemie, 7, 0.89% Angewandte Chemie 7 publications, 0.89%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 7, 0.89% Angewandte Chemie - International Edition 7 publications, 0.89%
	5 10 15 20 25 30 35 40 45

Citations by publishers

	50 100 150 200 250
Wiley	Wiley, 219, 27.72% Wiley 219 publications, 27.72%
Elsevier	Elsevier, 148, 18.73% Elsevier 148 publications, 18.73%
American Chemical Society (ACS)	American Chemical Society (ACS), 121, 15.32% American Chemical Society (ACS) 121 publications, 15.32%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 87, 11.01% Royal Society of Chemistry (RSC) 87 publications, 11.01%
Springer Nature	Springer Nature, 82, 10.38% Springer Nature 82 publications, 10.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 28, 3.54% Multidisciplinary Digital Publishing Institute (MDPI) 28 publications, 3.54%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 20, 2.53% American Association for the Advancement of Science (AAAS) 20 publications, 2.53%
IOP Publishing	IOP Publishing, 18, 2.28% IOP Publishing 18 publications, 2.28%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 17, 2.15% American Institute of Physics (AIP) 17 publications, 2.15%
Frontiers Media S.A.	Frontiers Media S.A., 4, 0.51% Frontiers Media S.A. 4 publications, 0.51%
American Physical Society (APS)	American Physical Society (APS), 3, 0.38% American Physical Society (APS) 3 publications, 0.38%
Oxford University Press	Oxford University Press, 2, 0.25% Oxford University Press 2 publications, 0.25%
Tsinghua University Press	Tsinghua University Press, 1, 0.13% Tsinghua University Press 1 publication, 0.13%
The Electrochemical Society	The Electrochemical Society, 1, 0.13% The Electrochemical Society 1 publication, 0.13%
Shanghai Institute of Organic Chemistry	Shanghai Institute of Organic Chemistry, 1, 0.13% Shanghai Institute of Organic Chemistry 1 publication, 0.13%
Opto-Electronic Advances	Opto-Electronic Advances, 1, 0.13% Opto-Electronic Advances 1 publication, 0.13%
Walter de Gruyter	Walter de Gruyter, 1, 0.13% Walter de Gruyter 1 publication, 0.13%
Taylor & Francis	Taylor & Francis, 1, 0.13% Taylor & Francis 1 publication, 0.13%
The Royal Society	The Royal Society, 1, 0.13% The Royal Society 1 publication, 0.13%
Cambridge University Press	Cambridge University Press, 1, 0.13% Cambridge University Press 1 publication, 0.13%
Japan Society of Applied Physics	Japan Society of Applied Physics, 1, 0.13% Japan Society of Applied Physics 1 publication, 0.13%
IEEE	IEEE, 1, 0.13% IEEE 1 publication, 0.13%
	50 100 150 200 250

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Khenkin M. V. et al. Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures // Nature Energy. 2020. Vol. 5. No. 1. pp. 35-49.

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Khenkin M. V. et al. Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures // Nature Energy. 2020. Vol. 5. No. 1. pp. 35-49.

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TY - JOUR

DO - 10.1038/s41560-019-0529-5

UR - https://doi.org/10.1038%2Fs41560-019-0529-5

TI - Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

T2 - Nature Energy

AU - Khenkin, M. V.

AU - Katz, Eugene R.

AU - Abate, Antonio

AU - Bardizza, Giorgio

AU - Berry, Joseph J

AU - Brabec, Christoph

AU - Brunetti, Francesca

AU - Bulovic, Vladimir

AU - Burlingame, Quinn

AU - Carlo, Aldo di

AU - Cheacharoen, Rongrong

AU - Colsmann, Alexander

AU - Cros, Stephane

AU - Domanski, Konrad

AU - Dusza, Michał

AU - Fell, Christopher R.

AU - Forrest, Stephen R.

AU - Galagan, Yulia

AU - Di Girolamo, Diego

AU - Hagfeldt, Anders

AU - Von Hauff, Elizabeth

AU - Hoppe, Harald

AU - Kettle, Jeff

AU - Köbler, Hans

AU - Leite, Marina S

AU - Liu, Shengzhong

AU - Loo, Yueh-Lin

AU - Luther, Joseph M.

AU - Hannibal Madsen, Morten

AU - Manceau, Matthieu

AU - Matheron, Muriel

AU - McGehee, Michael

AU - Meitzner, Rico

AU - Nazeeruddin, M.

AU - M. F. Nogueira, Ana Margarida

AU - Odabaşı, Çağla

AU - Osherov, Anna

AU - Park, Nam-Gyu

AU - Reese, Matthew O

AU - De Rossi, Francesca

AU - Saliba, Michael

AU - Schubert, Ulrich S.

AU - Snaith, Henry

AU - Stranks, Samuel D.

AU - Tress, Wolfgang

AU - Troshin, Pavel A.

AU - Veenstra, Sjoerd

AU - Visoly-Fisher, I

AU - Walsh, Aron

AU - Watson, Trystan M.

AU - Xie, Haibing

AU - Yildirim, Ramazan

AU - Zakeeruddin, Shaik Mohammed

AU - Zhu, Kai

AU - Lira Cantú, Mónica

AU - Cheng, Yi-Bing

AU - Grätzel, Michael

AU - Ma, Chang Qi

AU - Turkovic, Vida

PY - 2020

DA - 2020/01/22 00:00:00

PB - Springer Nature

SP - 35-49

IS - 1

VL - 5

SN - 2058-7546

ER -

BibTex |

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@article{2020_Khenkin,

author = {M. V. Khenkin and Eugene R. Katz and Antonio Abate and Giorgio Bardizza and Joseph J Berry and Christoph Brabec and Francesca Brunetti and Vladimir Bulovic and Quinn Burlingame and Aldo di Carlo and Rongrong Cheacharoen and Alexander Colsmann and Stephane Cros and Konrad Domanski and Michał Dusza and Christopher R. Fell and Stephen R. Forrest and Yulia Galagan and Diego Di Girolamo and Anders Hagfeldt and Elizabeth Von Hauff and Harald Hoppe and Jeff Kettle and Hans Köbler and Marina S Leite and Shengzhong Liu and Yueh-Lin Loo and Joseph M. Luther and Morten Hannibal Madsen and Matthieu Manceau and Muriel Matheron and Michael McGehee and Rico Meitzner and M. Nazeeruddin and Ana Margarida M. F. Nogueira and Çağla Odabaşı and Anna Osherov and Nam-Gyu Park and Matthew O Reese and Francesca De Rossi and Michael Saliba and Ulrich S. Schubert and Henry Snaith and Samuel D. Stranks and Wolfgang Tress and Pavel A. Troshin and Sjoerd Veenstra and I Visoly-Fisher and Aron Walsh and Trystan M. Watson and Haibing Xie and Ramazan Yildirim and Shaik Mohammed Zakeeruddin and Kai Zhu and Mónica Lira Cantú and Yi-Bing Cheng and Michael Grätzel and Chang Qi Ma and Vida Turkovic},

title = {Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures},

journal = {Nature Energy},

year = {2020},

volume = {5},

publisher = {Springer Nature},

month = {jan},

url = {https://doi.org/10.1038%2Fs41560-019-0529-5},

number = {1},

pages = {35--49},

doi = {10.1038/s41560-019-0529-5}

}

MLA

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MLA Copy

Khenkin, M. V., et al. “Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures.” Nature Energy, vol. 5, no. 1, Jan. 2020, pp. 35-49. https://doi.org/10.1038%2Fs41560-019-0529-5.

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Publisher

Springer Nature

Journal

Nature Energy

Quartile SCImago

Quartile WOS

Impact factor

56.7

ISSN

20587546 (Electronic)

Labs

Laboratory of Functional Materials for Electronics and Medicine

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