A lithium superionic conductor
Noriaki Kamaya
1
,
Kenji Homma
1
,
Yuichiro Yamakawa
1
,
Masaaki Hirayama
1
,
Ryoji Kanno
1
,
Masao Yonemura
2
,
Takashi Kamiyama
2
,
Yuki Kato
3
,
Shigenori Hama
3
,
Koji Kawamoto
3
,
Akio Mitsui
4
Publication type: Journal Article
Publication date: 2011-07-31
scimago Q1
wos Q1
SJR: 14.204
CiteScore: 61.8
Impact factor: 38.5
ISSN: 14761122, 14764660
DOI:
10.1038/nmat3066
PubMed ID:
21804556
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Batteries are a key technology in modern society. They are used to power electric and hybrid electric vehicles and to store wind and solar energy in smart grids. Electrochemical devices with high energy and power densities can currently be powered only by batteries with organic liquid electrolytes. However, such batteries require relatively stringent safety precautions, making large-scale systems very complicated and expensive. The application of solid electrolytes is currently limited because they attain practically useful conductivities (10(-2) S cm(-1)) only at 50-80 °C, which is one order of magnitude lower than those of organic liquid electrolytes. Here, we report a lithium superionic conductor, Li(10)GeP(2)S(12) that has a new three-dimensional framework structure. It exhibits an extremely high lithium ionic conductivity of 12 mS cm(-1) at room temperature. This represents the highest conductivity achieved in a solid electrolyte, exceeding even those of liquid organic electrolytes. This new solid-state battery electrolyte has many advantages in terms of device fabrication (facile shaping, patterning and integration), stability (non-volatile), safety (non-explosive) and excellent electrochemical properties (high conductivity and wide potential window).
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Kamaya N. et al. A lithium superionic conductor // Nature Materials. 2011. Vol. 10. No. 9. pp. 682-686.
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Kamaya N., Homma K., Yamakawa Y., Hirayama M., Kanno R., Yonemura M., Kamiyama T., Kato Y., Hama S., Kawamoto K., Mitsui A. A lithium superionic conductor // Nature Materials. 2011. Vol. 10. No. 9. pp. 682-686.
Cite this
RIS
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TY - JOUR
DO - 10.1038/nmat3066
UR - https://doi.org/10.1038/nmat3066
TI - A lithium superionic conductor
T2 - Nature Materials
AU - Kamaya, Noriaki
AU - Homma, Kenji
AU - Yamakawa, Yuichiro
AU - Hirayama, Masaaki
AU - Kanno, Ryoji
AU - Yonemura, Masao
AU - Kamiyama, Takashi
AU - Kato, Yuki
AU - Hama, Shigenori
AU - Kawamoto, Koji
AU - Mitsui, Akio
PY - 2011
DA - 2011/07/31
PB - Springer Nature
SP - 682-686
IS - 9
VL - 10
PMID - 21804556
SN - 1476-1122
SN - 1476-4660
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Kamaya,
author = {Noriaki Kamaya and Kenji Homma and Yuichiro Yamakawa and Masaaki Hirayama and Ryoji Kanno and Masao Yonemura and Takashi Kamiyama and Yuki Kato and Shigenori Hama and Koji Kawamoto and Akio Mitsui},
title = {A lithium superionic conductor},
journal = {Nature Materials},
year = {2011},
volume = {10},
publisher = {Springer Nature},
month = {jul},
url = {https://doi.org/10.1038/nmat3066},
number = {9},
pages = {682--686},
doi = {10.1038/nmat3066}
}
Cite this
MLA
Copy
Kamaya, Noriaki, et al. “A lithium superionic conductor.” Nature Materials, vol. 10, no. 9, Jul. 2011, pp. 682-686. https://doi.org/10.1038/nmat3066.