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Nature Communications, volume 10, issue 1, publication number 677

Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts

dexin Yang 1, 2
Qinggong Zhu 1, 2
Chunjun Chen 1, 2
Huizhen Liu 1, 2
Zhimin Liu 1, 2
Zhijuan Zhao 1
Xiaoyu Zhang 1
Shoujie Liu 3
Buxing Han 1, 2
Publication typeJournal Article
Publication date2019-02-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor16.6
ISSN20411723, 20411723
General Chemistry
General Biochemistry, Genetics and Molecular Biology
Multidisciplinary
General Physics and Astronomy
Abstract
Production of methanol from electrochemical reduction of carbon dioxide is very attractive. However, achieving high Faradaic efficiency with high current density using facile prepared catalysts remains to be a challenge. Herein we report that copper selenide nanocatalysts have outstanding performance for electrochemical reduction of carbon dioxide to methanol, and the current density can be as high as 41.5 mA cm−2 with a Faradaic efficiency of 77.6% at a low overpotential of 285 mV. The copper and selenium in the catalysts cooperate very well for the formation of methanol. The current density is higher than those reported up to date with very high Faradaic efficiency for producing methanol. As far as we know, this is the first work for electrochemical reduction of carbon dioxide using copper selenide as the catalyst. While the conversion of CO2 to valuable, storable chemicals is attractive, there are few inexpensive and abundant catalysts that are also active and selective for liquid fuels. Here, the authors study copper selenide as a high-performing and efficient electrocatalyst for CO2 conversion to methanol.

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GOST |
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GOST Copy
Yang D. et al. Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts // Nature Communications. 2019. Vol. 10. No. 1. 677
GOST all authors (up to 50) Copy
Yang D., Zhu Q., Chen C., Liu H., Liu Z., Zhao Z., Zhang X., Liu S., Han B. Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts // Nature Communications. 2019. Vol. 10. No. 1. 677
RIS |
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RIS Copy
TY - JOUR
DO - 10.1038/s41467-019-08653-9
UR - https://www.nature.com/articles/s41467-019-08653-9
TI - Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts
T2 - Nature Communications
AU - Yang, dexin
AU - Zhu, Qinggong
AU - Chen, Chunjun
AU - Liu, Huizhen
AU - Liu, Zhimin
AU - Zhao, Zhijuan
AU - Zhang, Xiaoyu
AU - Liu, Shoujie
AU - Han, Buxing
PY - 2019
DA - 2019/02/08 00:00:00
PB - Springer Nature
IS - 1
VL - 10
PMID - 30737398
SN - 2041-1723
SN - 2041-1723
ER -
BibTex
Cite this
BibTex Copy
@article{2019_Yang,
author = {dexin Yang and Qinggong Zhu and Chunjun Chen and Huizhen Liu and Zhimin Liu and Zhijuan Zhao and Xiaoyu Zhang and Shoujie Liu and Buxing Han},
title = {Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts},
journal = {Nature Communications},
year = {2019},
volume = {10},
publisher = {Springer Nature},
month = {feb},
url = {https://www.nature.com/articles/s41467-019-08653-9},
number = {1},
doi = {10.1038/s41467-019-08653-9}
}
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