Open Access

Nature Communications, volume 13, issue 1, publication number 4097

Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries

Shraer Semyon D ^{1, 2}

Luchinin Nikita D. ²

Trussov Ivan A ²

Aksyonov D A ²

Morozov Anatolii V. ²

Ryazantsev Sergey V ^{1, 2}

Iarchuk Anna R ²

Morozova Polina A ²

Nikitina Victoria A. ^{1, 2}

Stevenson Keith J ²

Antipov Evgeny V. ^{1, 2}

Abakumov Artem M. ²

Fedotov Stanislav S. ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry, Lomonosov Moscow State University, Moscow, Russian Federation |

Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2022-07-14

Springer Nature

Journal: Nature Communications

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 20411723

DOI: 10.1038/s41467-022-31768-5

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PubMed ID: 35835761

General Chemistry

General Biochemistry, Genetics and Molecular Biology

Multidisciplinary

General Physics and Astronomy

Abstract

Polyanion compounds offer a playground for designing prospective electrode active materials for sodium-ion storage due to their structural diversity and chemical variety. Here, by combining a NaVPO₄F composition and KTiOPO₄-type framework via a low-temperature (e.g., 190 °C) ion-exchange synthesis approach, we develop a high-capacity and high-voltage positive electrode active material. When tested in a coin cell configuration in combination with a Na metal negative electrode and a NaPF₆-based non-aqueous electrolyte solution, this cathode active material enables a discharge capacity of 136 mAh g⁻¹ at 14.3 mA g⁻¹ with an average cell discharge voltage of about 4.0 V. Furthermore, a specific discharge capacity of 123 mAh g⁻¹ at 5.7 A g⁻¹ is also reported for the same cell configuration. Through ex situ and operando structural characterizations, we also demonstrate that the reversible Na-ion storage at the positive electrode occurs mostly via a solid-solution de/insertion mechanism.

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Citations by journals

	1 2 3 4
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 11.43% ACS applied materials & interfaces 4 publications, 11.43%
Advanced Functional Materials	Advanced Functional Materials, 3, 8.57% Advanced Functional Materials 3 publications, 8.57%
Energy Storage Materials	Energy Storage Materials, 2, 5.71% Energy Storage Materials 2 publications, 5.71%
Applied Nano	Applied Nano, 1, 2.86% Applied Nano 1 publication, 2.86%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 2.86% Journal of Energy Chemistry 1 publication, 2.86%
Materials Today	Materials Today, 1, 2.86% Materials Today 1 publication, 2.86%
Applied Surface Science	Applied Surface Science, 1, 2.86% Applied Surface Science 1 publication, 2.86%
Solid State Ionics	Solid State Ionics, 1, 2.86% Solid State Ionics 1 publication, 2.86%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2.86% Journal of Colloid and Interface Science 1 publication, 2.86%
Materials Horizons	Materials Horizons, 1, 2.86% Materials Horizons 1 publication, 2.86%
Materials Futures	Materials Futures, 1, 2.86% Materials Futures 1 publication, 2.86%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 1, 2.86% Journal of Solid State Chemistry 1 publication, 2.86%
Materials Today Communications	Materials Today Communications, 1, 2.86% Materials Today Communications 1 publication, 2.86%
Clean Technologies	Clean Technologies, 1, 2.86% Clean Technologies 1 publication, 2.86%
Nano Letters	Nano Letters, 1, 2.86% Nano Letters 1 publication, 2.86%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 2.86% Journal of the Electrochemical Society 1 publication, 2.86%
Advanced Science	Advanced Science, 1, 2.86% Advanced Science 1 publication, 2.86%
ACS Central Science	ACS Central Science, 1, 2.86% ACS Central Science 1 publication, 2.86%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 2.86% Chemical Engineering Journal 1 publication, 2.86%
Solid State Sciences	Solid State Sciences, 1, 2.86% Solid State Sciences 1 publication, 2.86%
Dalton Transactions	Dalton Transactions, 1, 2.86% Dalton Transactions 1 publication, 2.86%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 2.86% ACS Applied Nano Materials 1 publication, 2.86%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.86% Angewandte Chemie - International Edition 1 publication, 2.86%
Angewandte Chemie	Angewandte Chemie, 1, 2.86% Angewandte Chemie 1 publication, 2.86%
Energy and Environmental Science	Energy and Environmental Science, 1, 2.86% Energy and Environmental Science 1 publication, 2.86%
Materials	Materials, 1, 2.86% Materials 1 publication, 2.86%
Advanced Energy Materials	Advanced Energy Materials, 1, 2.86% Advanced Energy Materials 1 publication, 2.86%
New Journal of Chemistry	New Journal of Chemistry, 1, 2.86% New Journal of Chemistry 1 publication, 2.86%
Materials Today Energy	Materials Today Energy, 1, 2.86% Materials Today Energy 1 publication, 2.86%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12
Elsevier	Elsevier, 12, 34.29% Elsevier 12 publications, 34.29%
Wiley	Wiley, 7, 20% Wiley 7 publications, 20%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 20% American Chemical Society (ACS) 7 publications, 20%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 11.43% Royal Society of Chemistry (RSC) 4 publications, 11.43%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 8.57% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 8.57%
IOP Publishing	IOP Publishing, 1, 2.86% IOP Publishing 1 publication, 2.86%
The Electrochemical Society	The Electrochemical Society, 1, 2.86% The Electrochemical Society 1 publication, 2.86%
	2 4 6 8 10 12

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Shraer S. D. et al. Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries // Nature Communications. 2022. Vol. 13. No. 1. 4097

GOST all authors (up to 50) Copy

Shraer S. D., Luchinin N. D., Trussov I. A., Aksyonov D. A., Morozov A. V., Ryazantsev S. V., Iarchuk A. R., Morozova P. A., Nikitina V. A., Stevenson K. J., Antipov E. V., Abakumov A. M., Fedotov S. S. Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries // Nature Communications. 2022. Vol. 13. No. 1. 4097

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TY - JOUR

DO - 10.1038/s41467-022-31768-5

UR - https://doi.org/10.1038%2Fs41467-022-31768-5

TI - Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries

T2 - Nature Communications

AU - Shraer, Semyon D

AU - Trussov, Ivan A

AU - Aksyonov, D A

AU - Morozov, Anatolii V.

AU - Ryazantsev, Sergey V

AU - Iarchuk, Anna R

AU - Morozova, Polina A

AU - Nikitina, Victoria A.

AU - Stevenson, Keith J

AU - Antipov, Evgeny V.

AU - Abakumov, Artem M.

AU - Fedotov, Stanislav S.

AU - Luchinin, Nikita D.

PY - 2022

DA - 2022/07/14 00:00:00

PB - Springer Nature

IS - 1

VL - 13

PMID - 35835761

SN - 2041-1723

ER -

BibTex

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@article{2022_Shraer,

author = {Semyon D Shraer and Ivan A Trussov and D A Aksyonov and Anatolii V. Morozov and Sergey V Ryazantsev and Anna R Iarchuk and Polina A Morozova and Victoria A. Nikitina and Keith J Stevenson and Evgeny V. Antipov and Artem M. Abakumov and Stanislav S. Fedotov and Nikita D. Luchinin},

title = {Development of vanadium-based polyanion positive electrode active materials for high-voltage sodium-based batteries},

journal = {Nature Communications},

year = {2022},

volume = {13},

publisher = {Springer Nature},

month = {jul},

url = {https://doi.org/10.1038%2Fs41467-022-31768-5},

number = {1},

doi = {10.1038/s41467-022-31768-5}

}

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Springer Nature

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Nature Communications

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16.6

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20411723 (Print)

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