Open Access

Nature Communications, volume 14, issue 1, publication number 6296

Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries

Qian Wu ^{1, 2}

Mandi Fang ³

Shizhe Jiao ⁴

Siyuan Li ^{1, 2}

Shichao Zhang ^{1, 2}

Zeyu Shen ^{1, 2}

Shulan Mao ^{1, 2}

Jiale Mao ^{1, 2}

Jiahui Zhang ^{1, 2}

Yuanzhong Tan ⁵

Kang Shen ⁵

Jiaxing Lv ⁵

Wei Hu ⁴

Yi He ^{3, 6}

Yingying Lu ^{1, 2}

Hide authors affiliations Show authors affiliations: 6 affiliations

ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou, China |

State Key Laboratory of Chemical Engineering, Institute of Pharmaceutical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, China |

College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, China |

⁴

School of Future Technology, Department of Chemical Physics, and Anhui Center for Applied Mathematics, University of Science and Technology of China, Hefei, China |

⁵

Innovation Research Institute of Technology Center, Zhejiang Xinan Chemical Industrial Group Co. ltd, Hangzhou, China |

⁶

Department of Chemical Engineering, University of Washington, Seattle, USA |

Publication type: Journal Article

Publication date: 2023-10-09

Springer Nature

Journal: Nature Communications

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 20411723, 20411723

DOI: 10.1038/s41467-023-41808-3

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General Chemistry

General Biochemistry, Genetics and Molecular Biology

Multidisciplinary

General Physics and Astronomy

Abstract

Solid polymer electrolytes with large-scale processability and interfacial compatibility are promising candidates for solid-state lithium metal batteries. Among various systems, poly(vinylidene fluoride)-based polymer electrolytes with residual solvent are appealing for room-temperature battery operations. However, their porous structure and limited ionic conductivity hinder practical application. Herein, we propose a phase regulation strategy to disrupt the symmetry of poly(vinylidene fluoride) chains and obtain the dense composite electrolyte through the incorporation of MoSe₂ sheets. The electrolyte with high dielectric constant can optimize the solvation structures to achieve high ionic conductivity and low activation energy. The in-situ reactions between MoSe₂ and Li metal generate Li₂Se fast conductor in solid electrolyte interphase, which improves the Coulombic efficiency and interfacial kinetics. The solid-state Li||Li cells achieve robust cycling at 1 mA cm⁻², and the Li||LiNi_0.8Co_0.1Mn_0.1O₂ full cells show practical performance at high rate (3C), high loading (2.6 mAh cm⁻²) and in pouch cell.

By date By citations

Top-30

Citations by journals

	1 2 3
Advanced Energy Materials	Advanced Energy Materials, 3, 9.68% Advanced Energy Materials 3 publications, 9.68%
Advanced Functional Materials	Advanced Functional Materials, 2, 6.45% Advanced Functional Materials 2 publications, 6.45%
Energy Storage Materials	Energy Storage Materials, 2, 6.45% Energy Storage Materials 2 publications, 6.45%
ACS Energy Letters	ACS Energy Letters, 2, 6.45% ACS Energy Letters 2 publications, 6.45%
Journal of Power Sources	Journal of Power Sources, 2, 6.45% Journal of Power Sources 2 publications, 6.45%
Nature Energy	Nature Energy, 1, 3.23% Nature Energy 1 publication, 3.23%
Nano-Micro Letters	Nano-Micro Letters, 1, 3.23% Nano-Micro Letters 1 publication, 3.23%
Sustainable Energy and Fuels	Sustainable Energy and Fuels, 1, 3.23% Sustainable Energy and Fuels 1 publication, 3.23%
Advanced Nanocomposites	Advanced Nanocomposites, 1, 3.23% Advanced Nanocomposites 1 publication, 3.23%
Angewandte Chemie	Angewandte Chemie, 1, 3.23% Angewandte Chemie 1 publication, 3.23%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 3.23% Angewandte Chemie - International Edition 1 publication, 3.23%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 3.23% Journal of Materials Chemistry A 1 publication, 3.23%
Energy and Environmental Science	Energy and Environmental Science, 1, 3.23% Energy and Environmental Science 1 publication, 3.23%
Advanced Materials	Advanced Materials, 1, 3.23% Advanced Materials 1 publication, 3.23%
Current Opinion in Electrochemistry	Current Opinion in Electrochemistry, 1, 3.23% Current Opinion in Electrochemistry 1 publication, 3.23%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 3.23% Chinese Chemical Letters 1 publication, 3.23%
Advanced Science	Advanced Science, 1, 3.23% Advanced Science 1 publication, 3.23%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 3.23% ACS applied materials & interfaces 1 publication, 3.23%
Interdisciplinary Materials	Interdisciplinary Materials, 1, 3.23% Interdisciplinary Materials 1 publication, 3.23%
Rare Metals	Rare Metals, 1, 3.23% Rare Metals 1 publication, 3.23%
Nano Energy	Nano Energy, 1, 3.23% Nano Energy 1 publication, 3.23%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.23% Russian Chemical Reviews 1 publication, 3.23%
Carbon Neutrality	Carbon Neutrality, 1, 3.23% Carbon Neutrality 1 publication, 3.23%
ACS Nano	ACS Nano, 1, 3.23% ACS Nano 1 publication, 3.23%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 1, 3.23% Sensors and Actuators, B: Chemical 1 publication, 3.23%
	1 2 3

Citations by publishers

	2 4 6 8 10
Wiley	Wiley, 10, 32.26% Wiley 10 publications, 32.26%
Elsevier	Elsevier, 9, 29.03% Elsevier 9 publications, 29.03%
Springer Nature	Springer Nature, 4, 12.9% Springer Nature 4 publications, 12.9%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 12.9% American Chemical Society (ACS) 4 publications, 12.9%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 9.68% Royal Society of Chemistry (RSC) 3 publications, 9.68%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.23% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.23%
	2 4 6 8 10

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Wu Q. et al. Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries // Nature Communications. 2023. Vol. 14. No. 1. 6296

GOST all authors (up to 50) Copy

Wu Q., Fang M., Jiao S., Li S., Zhang S., Shen Z., Mao S., Mao J., Zhang J., Tan Y., Shen K., Lv J., Hu W., He Y., Lu Y. Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries // Nature Communications. 2023. Vol. 14. No. 1. 6296

RIS |

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RIS Copy

TY - JOUR

DO - 10.1038/s41467-023-41808-3

UR - https://doi.org/10.1038/s41467-023-41808-3

TI - Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries

T2 - Nature Communications

AU - Wu, Qian

AU - Fang, Mandi

AU - Jiao, Shizhe

AU - Li, Siyuan

AU - Zhang, Shichao

AU - Shen, Zeyu

AU - Mao, Shulan

AU - Mao, Jiale

AU - Zhang, Jiahui

AU - Tan, Yuanzhong

AU - Shen, Kang

AU - Lv, Jiaxing

AU - Hu, Wei

AU - He, Yi

AU - Lu, Yingying

PY - 2023

DA - 2023/10/09 00:00:00

PB - Springer Nature

IS - 1

VL - 14

SN - 2041-1723

ER -

BibTex

Cite this

BibTex Copy

@article{2023_Wu,

author = {Qian Wu and Mandi Fang and Shizhe Jiao and Siyuan Li and Shichao Zhang and Zeyu Shen and Shulan Mao and Jiale Mao and Jiahui Zhang and Yuanzhong Tan and Kang Shen and Jiaxing Lv and Wei Hu and Yi He and Yingying Lu},

title = {Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries},

journal = {Nature Communications},

year = {2023},

volume = {14},

publisher = {Springer Nature},

month = {oct},

url = {https://doi.org/10.1038/s41467-023-41808-3},

number = {1},

doi = {10.1038/s41467-023-41808-3}

}

Found error?

Publisher

Springer Nature

Journal

Nature Communications

Quartile SCImago

Quartile WOS

Impact factor

16.6

ISSN

20411723 (Print)
20411723 (Electronic)

Profiles

Hu, Wei