Nature Energy

, volume 5 , issue 1 , pages 35-49

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

M. V. Khenkin ^{1, 2}

Eugene R. Katz ^{1, 3}

Antonio Abate ⁴

Giorgio Bardizza ⁵

Joseph J Berry ⁶

Christoph Brabec ^{7, 8}

Francesca Brunetti ⁹

Vladimir Bulovic ¹⁰

Quinn Burlingame ¹¹

Aldo di Carlo ⁹

Rongrong Cheacharoen ¹²

Yi-Bing Cheng ¹³

Alexander Colsmann ¹⁴

Stephane Cros ¹⁵

Konrad Domanski ¹⁶

Michał Dusza ¹⁷

Christopher R. Fell ¹⁸

Stephen R. Forrest ^{19, 20, 21}

Yulia Galagan ²²

Diego Di Girolamo ^{9, 23}

Michael Grätzel ²⁴

Anders Hagfeldt ²⁵

Elizabeth Von Hauff ²⁶

Harald Hoppe ²⁷

Jeff Kettle ²⁸

Hans Köbler ⁴

Marina S Leite ^{29, 30}

Shengzhong Liu ^{31, 32}

Yueh-Lin Loo ^{11, 33}

Joseph M. Luther ⁶

Chang Qi Ma ³⁴

Morten Hannibal Madsen ³⁵

Matthieu Manceau ¹⁵

Muriel Matheron ¹⁵

Michael McGehee ^{6, 36}

Rico Meitzner ²⁷

M. Nazeeruddin ³⁷

Ana Margarida M. F. Nogueira ³⁸

Çağla Odabaşı ³⁹

Anna Osherov ¹⁰

Nam-Gyu Park ⁴⁰

Matthew O Reese ⁶

Francesca De Rossi ^{9, 41}

Michael Saliba ^{42, 43}

Ulrich S. Schubert ^{27, 44}

Henry Snaith ⁴⁵

Samuel D. Stranks ⁴⁶

Wolfgang Tress ²⁵

Pavel A. Troshin ^{47, 48}

Vida Turkovic ³⁵

Sjoerd Veenstra ²²

I Visoly-Fisher ^{1, 3}

Aron Walsh ^{49, 50}

Trystan M. Watson ⁴¹

Haibing Xie ⁵¹

Ramazan Yildirim ³⁹

Shaik Mohammed Zakeeruddin ²⁴

Kai Zhu ⁶

Mónica Lira Cantú ⁵¹

Hide authors affiliations Show authors affiliations: 51 affiliations

Department of Solar Energy and Environmental Physics, Swiss Institute for Dryland Environmental and Energy Research, J. Blaustein Institutes for Desert Research, Ben-Gurion University of the Negev, Midreshet Ben-Gurion, Israel |

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, PVcomB, Berlin, Germany |

Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Be’er- Sheva, Israel |

⁴

Helmholtz-Zentrum Berlin Für Materialien Und Energie GmbH, Berlin, Germany |

⁵

European Commission, Joint Research Centre (JRC), Ispra, Italy |

⁶

National Renewable Energy Laboratory, Golden, USA |

⁷

Department of Materials Science and Engineering, Friedrich Alexander University Erlangen Nürnberg, Erlangen, Germany |

⁸

Helmholtz Institute Erlangen-Nürnberg (HI-ErN), Forschungszentrum Jülich (FZJ), Erlangen, Germany

Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy

Forschungszentrum Jülich

⁹

CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata, Rome, Italy |

¹⁰

Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, USA |

¹¹

Andlinger Center for Energy & The Environment, Princeton University, Princeton, USA |

¹²

Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok, Thailand |

¹³

State key laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China |

¹⁴

Light Technology Institute, Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany |

¹⁵

University of Grenoble Alpes, CEA, LITEN, INES, Le Bourget du Lac, France |

¹⁶

Fluxim AG, Winterthur, Switzerland |

¹⁷

Saule Technologies, Wroclaw Technology Park, Wroclaw, Poland |

¹⁸

CSIRO Energy, Mayfield West, Australia |

¹⁹

Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, USA |

²⁰

Department of Physics, University of Michigan, Ann Arbor, USA |

²¹

Department of Materials Science and Engineering, University Of Michigan, Ann Arbor, USA |

²²

TNO - Solliance, High Tech Campus, Eindhoven, The Netherlands |

²³

Department of Chemistry, University of Rome La Sapienza, Rome, Italy |

²⁴

Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland |

²⁵

Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland |

²⁶

Department of Physics and Astronomy, Vrije Universiteit Amsterdam, Amsterdam, the Netherlands |

²⁷

Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller University Jena, Jena, Germany |

²⁸

School of Electronic Engineering, Bangor University, Bangor, Gwynedd, UK |

²⁹

Department of Materials Science and Engineering, Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, USA |

³⁰

Department of Materials Science and Engineering, University of California, Davis, USA |

³¹

Dalian National Laboratory for Clean Energy/Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China |

³²

Key Laboratory for Advanced Energy Devices; Shaanxi Engineering Lab for Advanced Energy Technology; Institute for Advanced Energy Materials; School of Materials Science and Engineering, Shaanxi Normal University, Xi’an, China |

³³

Department of Chemical and Biological Engineering, Princeton University, Princeton, USA |

³⁴

Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS), Suzhou, China |

³⁵

SDU nanoSYD, Mads Clausen Institute, University of Southern Denmark, Sønderborg, Denmark |

³⁶

University of Colorado Boulder, Boulder, USA |

³⁷

Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Sion, Switzerland |

³⁸

Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas – UNICAMP, Campinas, Brazil |

³⁹

Department of Chemical Engineering, BoğaziÇi University, Bebek, Istanbul, Turkey |

⁴⁰

School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon, Korea |

⁴¹

SPECIFIC, College of Engineering, Swansea University, Bay Campus, Swansea, UK |

⁴²

Institute of Materials Science, Technical University of Darmstadt, Darmstadt, Germany |

⁴³

IEK-5 Photovoltaik, Forschungszentrum Jülich GmbH, Jülich, Germany |

⁴⁴

Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Jena, Germany |

⁴⁵

Clarendon Laboratory, University of Oxford, Oxford, UK |

⁴⁶

Cavendish laboratory, University of Cambridge, Cambridge, UK |

⁴⁷

Skolkovo Institute of Science and technology, Moscow, Russia |

⁴⁸

IPCP RAS, Chernogolovka, Russia |

⁴⁹

Department of materials, Imperial College London, London, UK |

⁵⁰

Department of Materials Science and Engineering, Yonsei University, Seoul, Korea |

⁵¹

Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Bellaterra, Spain

Barcelona Institute for Science and Technology

Catalan Institute of Nanoscience and Nanotechnology

Publication type: Journal Article

Publication date: 2020-01-22

Springer Nature

Nature Energy

scimago Q1

wos Q1

SJR: 17.599

CiteScore: 73.0

Impact factor: 60.1

ISSN: 20587546

DOI: 10.1038/s41560-019-0529-5

Copy DOI

Electronic, Optical and Magnetic Materials

Energy Engineering and Power Technology

Fuel Technology

Renewable Energy, Sustainability and the Environment

Abstract

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

Found

8 citations

Saranin Danila

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PhD in Physics and Mathematics

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National University of Science & Technology (MISiS)

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PhD in Engineering

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National University of Science & Technology (MISiS)

Research and Practical Clinical Center for Diagnostics and Telemedicine Technologies of the Moscow Health Care Department

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luchnikov Lev

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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

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National University of Science & Technology (MISiS)

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Nasibulin Albert

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Skolkovo Institute of Science and Technology

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National University of Science & Technology (MISiS)

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Kozlov Sergey

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Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences

Research interests

Hybrid perovskites

Nanostructures

Perovskite solar panels

Photovoltaics

Physics of nanostructures

Solar energy

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Zhidkov Ivan

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PhD in Physics and Mathematics, associate professor

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h-index: 29

Ural Federal University

M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences

Research interests

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Ishteev Arthur

299 publications, 4 566 citations

h-index: 33

National University of Science & Technology (MISiS)

N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

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Akkuratov Alexander

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h-index: 14

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

Research interests

Microelectronics

1 citation

Korsunsky Alexander

DSc in Physics and Mathematics, professor

573 publications, 11 059 citations

h-index: 54

University of Oxford

Skolkovo Institute of Science and Technology

1 citation

Marunchenko Alexandr

11 publications, 97 citations, 4 reviews

h-index: 6

Lund University

ITMO University

1 citation

Kavanagh Seán

57 publications, 1 436 citations, 19 reviews

h-index: 21

Harvard University

University College London

Imperial College London

University of Oxford

Research interests

Computational chemistry

Point defects

Solar energy

Theoretical Chemistry

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Petrov Andrey

PhD in Chemistry

52 publications, 1 132 citations

h-index: 16

Lomonosov Moscow State University

Research interests

Hybrid perovskites

Perovskite solar cells

1 citation

Argunov Efim

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PhD in Physics and Mathematics

22 publications, 66 citations

h-index: 5

National University of Science & Technology (MISiS)

1 citation

Komaricheva Tatiana

3 publications, 99 citations

h-index: 3

National University of Science & Technology (MISiS)

1 citation

Papkovskaya Elizaveta

7 publications, 74 citations

h-index: 4

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

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Das Chittaranjan

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GOST |

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GOST Copy

Khenkin M. V. et al. Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures // Nature Energy. 2020. Vol. 5. No. 1. pp. 35-49.

GOST all authors (up to 50) Copy

Khenkin M. V. et al. Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures // Nature Energy. 2020. Vol. 5. No. 1. pp. 35-49.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1038/s41560-019-0529-5

UR - https://doi.org/10.1038/s41560-019-0529-5

TI - Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

T2 - Nature Energy

AU - Khenkin, M. V.

AU - Katz, Eugene R.

AU - Abate, Antonio

AU - Bardizza, Giorgio

AU - Berry, Joseph J

AU - Brabec, Christoph

AU - Brunetti, Francesca

AU - Bulovic, Vladimir

AU - Burlingame, Quinn

AU - Carlo, Aldo di

AU - Cheacharoen, Rongrong

AU - Cheng, Yi-Bing

AU - Colsmann, Alexander

AU - Cros, Stephane

AU - Domanski, Konrad

AU - Dusza, Michał

AU - Fell, Christopher R.

AU - Forrest, Stephen R.

AU - Galagan, Yulia

AU - Di Girolamo, Diego

AU - Grätzel, Michael

AU - Hagfeldt, Anders

AU - Von Hauff, Elizabeth

AU - Hoppe, Harald

AU - Kettle, Jeff

AU - Köbler, Hans

AU - Leite, Marina S

AU - Liu, Shengzhong

AU - Loo, Yueh-Lin

AU - Luther, Joseph M.

AU - Ma, Chang Qi

AU - Hannibal Madsen, Morten

AU - Manceau, Matthieu

AU - Matheron, Muriel

AU - McGehee, Michael

AU - Meitzner, Rico

AU - Nazeeruddin, M.

AU - M. F. Nogueira, Ana Margarida

AU - Odabaşı, Çağla

AU - Osherov, Anna

AU - Park, Nam-Gyu

AU - Reese, Matthew O

AU - De Rossi, Francesca

AU - Saliba, Michael

AU - Schubert, Ulrich S.

AU - Snaith, Henry

AU - Stranks, Samuel D.

AU - Tress, Wolfgang

AU - Troshin, Pavel A.

AU - Turkovic, Vida

AU - Veenstra, Sjoerd

AU - Visoly-Fisher, I

AU - Walsh, Aron

AU - Watson, Trystan M.

AU - Xie, Haibing

AU - Yildirim, Ramazan

AU - Zakeeruddin, Shaik Mohammed

AU - Zhu, Kai

AU - Lira Cantú, Mónica

PY - 2020

DA - 2020/01/22

PB - Springer Nature

SP - 35-49

IS - 1

VL - 5

SN - 2058-7546

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Khenkin,

author = {M. V. Khenkin and Eugene R. Katz and Antonio Abate and Giorgio Bardizza and Joseph J Berry and Christoph Brabec and Francesca Brunetti and Vladimir Bulovic and Quinn Burlingame and Aldo di Carlo and Rongrong Cheacharoen and Yi-Bing Cheng and Alexander Colsmann and Stephane Cros and Konrad Domanski and Michał Dusza and Christopher R. Fell and Stephen R. Forrest and Yulia Galagan and Diego Di Girolamo and Michael Grätzel and Anders Hagfeldt and Elizabeth Von Hauff and Harald Hoppe and Jeff Kettle and Hans Köbler and Marina S Leite and Shengzhong Liu and Yueh-Lin Loo and Joseph M. Luther and Chang Qi Ma and Morten Hannibal Madsen and Matthieu Manceau and Muriel Matheron and Michael McGehee and Rico Meitzner and M. Nazeeruddin and Ana Margarida M. F. Nogueira and Çağla Odabaşı and Anna Osherov and Nam-Gyu Park and Matthew O Reese and Francesca De Rossi and Michael Saliba and Ulrich S. Schubert and Henry Snaith and Samuel D. Stranks and Wolfgang Tress and Pavel A. Troshin and Vida Turkovic and others},

title = {Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures},

journal = {Nature Energy},

year = {2020},

volume = {5},

publisher = {Springer Nature},

month = {jan},

url = {https://doi.org/10.1038/s41560-019-0529-5},

number = {1},

pages = {35--49},

doi = {10.1038/s41560-019-0529-5}

}

MLA

Cite this

MLA Copy

Khenkin, M. V., et al. “Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures.” Nature Energy, vol. 5, no. 1, Jan. 2020, pp. 35-49. https://doi.org/10.1038/s41560-019-0529-5.

Publisher

Springer Nature

Journal

Nature Energy

scimago Q1

wos Q1

SJR

17.599

CiteScore

73.0

Impact factor

60.1

ISSN

20587546 (Electronic)

Labs

Laboratory of Functional Materials for Electronics and Medicine

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