Nature Materials, volume 20, issue 9, pages 1255-1263
Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways
Ying Wang
1
,
Curt J Zanelotti
1
,
Xiaoen Wang
2
,
Robert Kerr
2
,
Liyu Jin
2
,
Wang Hay H. Kan
3
,
Theo J Dingemans
4
,
Maria Forsyth
2
,
Louis A. Madsen
1
4
Department of Applied Physical Sciences, University of North Carolina at Chapel Hill, Chapel Hill, USA
|
Publication type: Journal Article
Publication date: 2021-05-03
Journal:
Nature Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 41.2
ISSN: 14761122, 14764660
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
A critical challenge for next-generation lithium-based batteries lies in development of electrolytes that enable thermal safety along with the use of high-energy-density electrodes. We describe molecular ionic composite electrolytes based on an aligned liquid crystalline polymer combined with ionic liquids and concentrated Li salt. This high strength (200 MPa) and non-flammable solid electrolyte possesses outstanding Li+ conductivity (1 mS cm−1 at 25 °C) and electrochemical stability (5.6 V versus Li|Li+) while suppressing dendrite growth and exhibiting low interfacial resistance (32 Ω cm2) and overpotentials (≤120 mV at 1 mA cm−2) during Li symmetric cell cycling. A heterogeneous salt doping process modifies a locally ordered polymer–ion assembly to incorporate an inter-grain network filled with defective LiFSI and LiBF4 nanocrystals, strongly enhancing Li+ conduction. This modular material fabrication platform shows promise for safe and high-energy-density energy storage and conversion applications, incorporating the fast transport of ceramic-like conductors with the superior flexibility of polymer electrolytes. Developing safe electrolytes compatible with high-energy-density electrodes is key for the next generation of lithium-based batteries. Stable solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways are now proposed.
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Citations by publishers
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Wang Y. et al. Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways // Nature Materials. 2021. Vol. 20. No. 9. pp. 1255-1263.
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Wang Y., Zanelotti C. J., Wang X., Kerr R., Jin L., Kan W. H. H., Dingemans T. J., Forsyth M., Madsen L. A. Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways // Nature Materials. 2021. Vol. 20. No. 9. pp. 1255-1263.
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TY - JOUR
DO - 10.1038/s41563-021-00995-4
UR - https://doi.org/10.1038/s41563-021-00995-4
TI - Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways
T2 - Nature Materials
AU - Wang, Ying
AU - Zanelotti, Curt J
AU - Wang, Xiaoen
AU - Kerr, Robert
AU - Jin, Liyu
AU - Kan, Wang Hay H.
AU - Dingemans, Theo J
AU - Forsyth, Maria
AU - Madsen, Louis A.
PY - 2021
DA - 2021/05/03 00:00:00
PB - Springer Nature
SP - 1255-1263
IS - 9
VL - 20
SN - 1476-1122
SN - 1476-4660
ER -
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@article{2021_Wang,
author = {Ying Wang and Curt J Zanelotti and Xiaoen Wang and Robert Kerr and Liyu Jin and Wang Hay H. Kan and Theo J Dingemans and Maria Forsyth and Louis A. Madsen},
title = {Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways},
journal = {Nature Materials},
year = {2021},
volume = {20},
publisher = {Springer Nature},
month = {may},
url = {https://doi.org/10.1038/s41563-021-00995-4},
number = {9},
pages = {1255--1263},
doi = {10.1038/s41563-021-00995-4}
}
Cite this
MLA
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Wang, Ying, et al. “Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways.” Nature Materials, vol. 20, no. 9, May. 2021, pp. 1255-1263. https://doi.org/10.1038/s41563-021-00995-4.